Synthesis and characterization of glyceryl monooleate-based polyester

Puyou Jia; Caiying Bo; Lihong Hu; Yonghong Zhou

Korean Journal of Chemical Engineering, Vol.32, No.3, 547-551, March, 2015

DOI10.1007/s11814-014-0214-0 Export Citation

Synthesis and characterization of glyceryl monooleate-based polyester

Puyou Jia¹, Caiying Bo¹, Lihong Hu^{1, 2}, and Yonghong Zhou^{1, †}

¹Institute of Chemical Industry of Forest Products, Chinese Academy of Forest (CAF), Jiangsu Province, Nanjing 210042, China
²Institute of New Technology of Forestry, Chinese Academy of Forest (CAF), Beijing 100091, China

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A unique biobased polyester poly(succinic acid-glyceryl monooleate) (PSAGMO) was synthesized and characterized from succinic acid (SA) and glyceryl monooleate (GMO). The polyester was characterized by gel permeation chromatography (GPC), Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic response spectroscopy (NMR). The polyester was used as the plasticizer of poly (vinyl chloride) (PVC). The mechanical properties and the thermodynamic properties of the blends were characterized. The TG-DTA data indicated that the thermal degradation temperature (Td) of PVC blends plasticized with PSAGMO could increase from 249.3 ℃ to 255.6 ℃. The DMA showed that the glass transition temperature (Tg) of the PVC blends decreased from 49.5 ℃ to 35 ℃. The mechanical properties indicated that the PSAGMO could decrease the tensile strength and increase the elongation at break of the PVC blends. This study may lead to the development of new type of PVC plasticizer based on renewable resource.

Keywords:Polyester;Poly(vinyl chloride);Blends;Thermal Stability

[References]

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Djordjevic I, Choudhury NR, Dutta NK, Kumar S, Polymer, 50(7), 1682 (2009)
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Isa MT, Ahmed AS, Aderemi BO, Composites: Part B, 53, 217 (2013)
Salimon J, Salih N, Yousif E, Arab. J. Chem., 5, 135 (2012)
Bordes P, Pollet E, Averous L, Prog. Polym. Sci., 34, 125 (2009)
Sharma V, Kundu PP, Prog. Polym. Sci., 31, 983 (2006)
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[Referenced By]

[1] Marcilla A, Garia S, Garcia-Quesdad JC, J. Anal. Appl. Pyrol., 7, 457 (2004)

[2] Latini G, Felice CD, Verrotti A, Reprod Toxicol., 19(1), 27 (2004)

[3] Ltini G, Biology of Neonat, 78, 269 (2000)

[4] Li JH, Ko YC, Kaohsiung J. Med. Sci., 28, 17 (2012)

[5] Chen YH, Fu SH, Huang JK, J. Food Drug. Anal., 21, 242 (2013)

[6] Hakkarainen M, Adv. Polym. Sci., 211, 159 (2008)

[7] Chiu FC, Min K, Polym. Int., 49, 223 (2000)

[8] Shah BL, Shertukde VVJ, Appl. Polym. Sci., 90, 3278 (2003)

[9] Choe S, Cha YJ, Lee HS, Yoon JS, Choi HJ, Polymer, 36(26), 4977 (1995)

[10] Sander MM, Nicolau A, Guzatto R, Polym Test, 31, 1077 (2012)

[11] Silva MAD, Vieira MGA, Macumoto ACG, Polym. Test, 30, 478 (2011)

[12] Li Y, Wang CM, Wang GJ, J. Wuhan Univ. Technol., 2, 100 (2008)

[13] Wu YM, Xie QW, Gao CH, Polym. Eng. Sci., DOI:10.1002/pen.23798. (2013)

[14] Djordjevic I, Choudhury NR, Dutta NK, Kumar S, Polymer, 50(7), 1682 (2009)

[15] Sathiskumar PS, Madras G, Polym. Degrad. Stabil., 96, 1695 (2011)

[16] Edlund U, Albertsson AC, Adv. Polym. Sci., 157, 67 (2002)

[17] Vieira MGA, Silva MA, Santos LO, Eur. Polym. J., 47, 254 (2011)

[18] Espinosa LM, Meier MAR, Eur. Polym. J., 47, 837 (2011)

[19] Sudesh K, Abe H, Doi Y, Prog. Polym. Sci., 25, 1503 (2000)

[20] Isa MT, Ahmed AS, Aderemi BO, Composites: Part B, 53, 217 (2013)

[21] Salimon J, Salih N, Yousif E, Arab. J. Chem., 5, 135 (2012)

[22] Bordes P, Pollet E, Averous L, Prog. Polym. Sci., 34, 125 (2009)

[23] Sharma V, Kundu PP, Prog. Polym. Sci., 31, 983 (2006)

[24] Chua SC, Xu XB, Guo Z, Process Biochem., 47, 1439 (2012)