전구체의 특성 및 AlF3 융제가 청색 발광의 BAM:Eu 형광체의 특성에 미치는 영향

조중상; 이상호; 강윤찬; Jung Sang Cho; Sang Ho Lee; Yun Chan Kang

Korean Journal of Materials Research, Vol.18, No.3, 137-142, March, 2008

DOI10.3740/MRSK.2008.18.3.137 Export Citation

전구체의 특성 및 AlF3 융제가 청색 발광의 BAM:Eu 형광체의 특성에 미치는 영향

Effects of the Characteristics of Precursor Powders and AlF3 Flux on the Properties of Blue-Emitting BAM:Eu Phosphor Powders

조중상, 이상호, 강윤찬 ^†

건국대학교 화학공학과, 서울특별시 광진구 화양동 1

Jung Sang Cho, Sang Ho Lee, and Yun Chan Kang^†

Department of Chemical Engineering, Konkuk University, 1 Hwayang-dong, Gwangjin-gu, Seoul 143-701, Korea

E-mail:

Blue-emitting BAM:Eu phosphor powders were formed by post-treatment of precursor powders with hollow or dense morphologies. The morphologies of the precursor powders obtained by spray pyrolysis were controlled by changing the preparation conditions and by changing the type of spray solution. The effects of the morphologies of the precursor powders on the characteristics of the BAM: Eu phosphor powders reacted with AlF3 flux were investigated. Precursor powders with a spherical shape and a hollow morphology produced BAM : Eu phosphor powders with a plate-like morphology, a fine size and a narrow size distribution. On the other hand, precursor powders with a spherical shape and dense morphology produced BAM : Eu phosphor powders with a plate-like morphology and a large size. AlF3 flux improved the photoluminescence intensities of the BAM : Eu phosphor powders. The photoluminescence intensity of the fine-sized BAM : Eu phosphor powders with a plate-like morphology was 90% of the commercial product under vacuum ultraviolet conditions.

Keywords:phosphor;spray pyrolysis;display materials;flux material

[References]

Kang KC, Park SB, J. Electrochem. Soc., 147(2), 799 (2000)
Jung KY, Lee DY, Kang YC, J. Lumin., 115, 91 (2005)
Zhou Y, Lin J, J. Solid State Chem., 178, 441 (2005)
Lee DY, Kang YC, Jung KY, Electrochem. Solid State Lett., 6(11), H27 (2003)
Shimomura Y, Kijima N, J. Electrochem. Soc., 151(8), H192 (2004)
Kang YC, Park SB, Jpn. J. Appl. Phys., 38(12B), L1541 (1999)
Kang YC, Roh HS, Bin Park S, Adv. Mater., 12(6), 451 (2000)
Shimomura Y, Kijima N, J. Electrochem. Soc., 151(4), H86 (2004)
Joffin N, Caillier B, Garcia A, Guillot P, Galy J, Fernandes A, Mauricot R, Dexpert-Ghys J, Opt. Mater., 28, 597 (2006)
Kang YC, Park SB, Lenggoro IW, Okuyama K, J. Electrochem. Soc., 146(7), 27447 (1999)
Jung KY, Han KH, Electrochem. Solid State Lett., 8(2), H17 (2005)
Jung DS, Hong SK, Lee HJ, Kang YC, Optical Mater., 28(5), 530 (2006)
Jung DS, Hong SK, Lee HJ, Kang YC, J. Alloy. Comp., 398, 309 (2005)
Kang YC, Roh HS, Park SB, Park HD, J. Europ. Ceram. Soc., 22(9-10), 1661 (2002)

[Related Articles]

[1] Kang KC, Park SB, J. Electrochem. Soc., 147(2), 799 (2000)

[2] Jung KY, Lee DY, Kang YC, J. Lumin., 115, 91 (2005)

[3] Zhou Y, Lin J, J. Solid State Chem., 178, 441 (2005)

[4] Lee DY, Kang YC, Jung KY, Electrochem. Solid State Lett., 6(11), H27 (2003)

[5] Shimomura Y, Kijima N, J. Electrochem. Soc., 151(8), H192 (2004)

[6] Kang YC, Park SB, Jpn. J. Appl. Phys., 38(12B), L1541 (1999)

[7] Kang YC, Roh HS, Bin Park S, Adv. Mater., 12(6), 451 (2000)

[8] Shimomura Y, Kijima N, J. Electrochem. Soc., 151(4), H86 (2004)

[9] Joffin N, Caillier B, Garcia A, Guillot P, Galy J, Fernandes A, Mauricot R, Dexpert-Ghys J, Opt. Mater., 28, 597 (2006)

[10] Kang YC, Park SB, Lenggoro IW, Okuyama K, J. Electrochem. Soc., 146(7), 27447 (1999)

[11] Jung KY, Han KH, Electrochem. Solid State Lett., 8(2), H17 (2005)

[12] Jung DS, Hong SK, Lee HJ, Kang YC, Optical Mater., 28(5), 530 (2006)

[13] Jung DS, Hong SK, Lee HJ, Kang YC, J. Alloy. Comp., 398, 309 (2005)

[14] Kang YC, Roh HS, Park SB, Park HD, J. Europ. Ceram. Soc., 22(9-10), 1661 (2002)