Glycothermal Synthesis and Characterization of 3Y-TZP Nanoparticles

Jeong-Hwan Song; Ju-Hee Lee

Korean Journal of Materials Research, Vol.19, No.8, 412-416, August, 2009

DOI10.3740/MRSK.2009.19.8.412 Export Citation

Glycothermal Synthesis and Characterization of 3Y-TZP Nanoparticles

Jeong-Hwan Song^†, and Ju-Hee Lee¹

Department of Information & Electronic Materials Engineering, PaiChai University, Daejeon 302-735, KOREA, Korea
¹Department of Dental Laboratory Technology, Daejeon Health Sciences College, Daejeon 300-711, KOREA, Korea

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In this study, 3 mol% yttria-tetragonal zirconia polycrystal (3Y-TZP) nanoparticles were synthesized by the glycothermal method under various reaction temperatures and times. The co-precipitated precursor of 3Y-TZP was prepared by adding NH4OH to starting solutions, and then the mixtures were placed in an autoclave reactor. Tetragonal yttria-doped zirconia nanoparticles were afforded through a glycothermal reaction at a temperature as low as 220 oC, using co-precipitated gels of ZrCl4 and YCl3 ·6H2O as precursors and 1,4-butanediol as the solvent. The synthesized 3Y-TZP particles were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and Raman spectroscopy. The 3Y-TZP particles have a stable tetragonal phase only at glycothermal temperatures above 200 oC. To investigate phase transition, the 3Y-TZP particles were heat treated from 400 to 1400 oC for 2 h. Raman analysis indicated that, after heat treatment, the tetragonal phase of the 3Y-TZP particles remained stable. The results of this study, therefore, suggest that 3Y-TZP powders can be prepared by the glycothermal method.

Keywords:3Y-TZP;nanoparticle;glycothermal;1,4-butanediol;Raman

[References]

Subbara EC, Science and Technology of Zirconia, Adv. in Ceramics vol.3, p.1-24, eds. Heuer AH, Hobbs LW (The American Ceramic Society, Columbus, Ohio, 1981). (1981)
Garvie RC, Hannink RH, Pascoe RT, Nature, 258, 703 (1975)
Garvie RC, J. Phys. Chem., 82, 218 (1978)
Holtappels P, Bagger C, J. Eur. Ceram. Soc., 22(1), 41 (2002)
Zhitomirsky I, Petric A, J. Eur. Ceram. Soc., 20(12), 2055 (2000)
Cai JC, Raptis C, Raptis YS, Anastassaki E, Phys. Rev. B, 51, 201 (1995)
Piconi C, Maccauro G, Biomaterials, 20, 1 (1999)
Green DJ, Hannink RH, Swain MV, Transformation toughening of ceramics. Boca Raton, Fl: CRC (1989). (1989)
Nieh TG, Wadsworth J, Acta Mater., 38, 1121 (1990)
Livage J, Beteille F, Rouse C, Chatry M, Davidson P, Acta Mater., 46, 743 (1998)
Quinelato AL, Longo E, Perazolli LA, Varela JA, J. Eur. Ceram. Soc., 20, 1077 (2000)
Juarez RE, Lamas DG, Lascalea GE, Walsoe de Reca NE, J. Eur. Ceram. Soc., 20, 133 (2000)
Dell’Agli G, Mascolo G, J. Eur. Ceram. Soc., 20, 139 (2000)
Segal D, Key Eng. Mater., 153, 241 (1998)
Inoue M, Tanino H, Kondo Y, Inui T, J. Am. Ceram. Soc., 72(2), 352 (1989)
Inoue M, J. Phys.: Condens. Matter, 16, S1291 (2004)
Chang C, Jon S, CIMTEC 2002 Proc., 4, 761 (2002)
Jung YJ, Lim DY, Nho JS, Cho SB, Riman RE, Lee BW, J. Cryst. Growth, 274(3-4), 638 (2005)
Gogotsi Y, Domnich V, in High-Pressure Surface Science and Engineering (Materials Science and Engineering), (CRC Press, Taylor & Francis, 2003) p. 467-520. (2003)

[Referenced By]

[1] Subbara EC, Science and Technology of Zirconia, Adv. in Ceramics vol.3, p.1-24, eds. Heuer AH, Hobbs LW (The American Ceramic Society, Columbus, Ohio, 1981). (1981)

[2] Garvie RC, Hannink RH, Pascoe RT, Nature, 258, 703 (1975)

[3] Garvie RC, J. Phys. Chem., 82, 218 (1978)

[4] Holtappels P, Bagger C, J. Eur. Ceram. Soc., 22(1), 41 (2002)

[5] Zhitomirsky I, Petric A, J. Eur. Ceram. Soc., 20(12), 2055 (2000)

[6] Cai JC, Raptis C, Raptis YS, Anastassaki E, Phys. Rev. B, 51, 201 (1995)

[7] Piconi C, Maccauro G, Biomaterials, 20, 1 (1999)

[8] Green DJ, Hannink RH, Swain MV, Transformation toughening of ceramics. Boca Raton, Fl: CRC (1989). (1989)

[9] Nieh TG, Wadsworth J, Acta Mater., 38, 1121 (1990)

[10] Livage J, Beteille F, Rouse C, Chatry M, Davidson P, Acta Mater., 46, 743 (1998)

[11] Quinelato AL, Longo E, Perazolli LA, Varela JA, J. Eur. Ceram. Soc., 20, 1077 (2000)

[12] Juarez RE, Lamas DG, Lascalea GE, Walsoe de Reca NE, J. Eur. Ceram. Soc., 20, 133 (2000)

[13] Dell’Agli G, Mascolo G, J. Eur. Ceram. Soc., 20, 139 (2000)

[14] Segal D, Key Eng. Mater., 153, 241 (1998)

[15] Inoue M, Tanino H, Kondo Y, Inui T, J. Am. Ceram. Soc., 72(2), 352 (1989)

[16] Inoue M, J. Phys.: Condens. Matter, 16, S1291 (2004)

[17] Chang C, Jon S, CIMTEC 2002 Proc., 4, 761 (2002)

[18] Jung YJ, Lim DY, Nho JS, Cho SB, Riman RE, Lee BW, J. Cryst. Growth, 274(3-4), 638 (2005)

[19] Gogotsi Y, Domnich V, in High-Pressure Surface Science and Engineering (Materials Science and Engineering), (CRC Press, Taylor & Francis, 2003) p. 467-520. (2003)