Catalytic wet peroxide oxidation of phenol over Ce-Zr-modified clays: Effect of the pillaring method

Saida Mnasri-Ghnimi; N. Frini-Srasra

Korean Journal of Chemical Engineering, Vol.32, No.1, 68-73, January, 2015

DOI10.1007/s11814-014-0204-2 Export Citation

Catalytic wet peroxide oxidation of phenol over Ce-Zr-modified clays: Effect of the pillaring method

Saida Mnasri-Ghnimi^{1, †}, and N. Frini-Srasra^{1, 2}

¹Laboratoire de Physico-chimie des Matériaux Minéraux et Leurs Applications, Centre National des Recherches en Sciences des Matériaux, Technopole Borj Cédria, BP 95-2050 Hammam Lif, Tunisia
²Départements de Chimie, Faculté des Sciences de Tunis, 1060 Tunis, Tunisia

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Preparation, characterization and catalytic activity of Zr-and Ce-Zr pillared clays with different method (direct, indirect, and under reflux), starting from Tunisian interstratified illite-smectite bentonite, are described. Zirconium pillared clays (Zr-PILC) revealed weaker thermal stability. To overcome this drawback, the addition of cerium (Ce) as the second metal component to Zr-PILC was attempted. Wet peroxide oxidation of phenol from industrial wastewaters was carried out over these catalysts. The catalysts were very efficient in the phenol oxidation reaction in diluted aqueous medium under mild experimental conditions (298 K and atmospheric pressure). The addition of Ce in the synthesis step of the inorganic polycations yielded a favorable effect on the pillaring of the materials, allowing the increase of the basal spacing and enhancing the catalytic activity of the solids. The pillared clays were characterized by XRD, chemical analysis, CEC, and N2 adsorption to 77 K. The acidity of the pillared clays was calculated from the adsorbed n-butyl amine.

Keywords:Pillared Clays;Zirconium;Cerium;Catalysis;Phenol Oxidation

[References]

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Mnasri S, Frini-Srasra N, Clay Miner., 47, 453 (2012)
Mnasri S, Frini-Srasra N, Inf. Phys. Technol., 58, 15 (2013)
Mnasri S, Frini-Srasra N, Surf. Eng. Appl. Electrochem., 49, 336 (2013)
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[Referenced By]

[1] Catrinescu C, Teodosiu C, Macoveanu M, Miehe_Brendle J, Le Dred R, Water Res., 37, 1154 (2003)

[2] Vaughan DEW, Lussier RJ, Magee SJJ, US Patent, 4,176,090 (1979)

[3] Booij E, Kloprogge TJ, van Veen JAR, Appl. Clay. Sci., 11, 155 (1996)

[4] Gil A, Gandia LM, Vicente MA, Catal. Rev.-Sci. Eng., 42(1-2), 145 (2000)

[5] Huerta L, Meyer A, Choren E, Micropor. Mesopor. Mater., 57, 219 (2003)

[6] Ben Chaabene S, Bergaoui L, Ghorbel A, Lambert JF, Grange P, Appl. Catal. A: Gen., 268(1-2), 25 (2004)

[7] Carriazo J, Guelou E, Barrault J, Tatibouet JM, Molina R, Moreno S, Water Res., 39, 3891 (2005)

[8] Carriazo J, Guelou E, Barrault J, Molina R, Moreno S, Catal. Today, 107-108, 126 (2005)

[9] Hernando MJ, Pesquera C, Blanco C, Gonzalez F, Chem. Mater., 13, 2154 (2001)

[10] Kim SK, Ihm SK, Ind. Eng. Chem. Res., 41(8), 1967 (2002)

[11] Mnasri S, Besbes N, Frini-Srasra N, Srasra E, C. R. Chem., 15, 437 (2012)

[12] Mnasri S, Frini-Srasra N, Clay Miner., 47, 453 (2012)

[13] Mnasri S, Frini-Srasra N, Inf. Phys. Technol., 58, 15 (2013)

[14] Mnasri S, Frini-Srasra N, Surf. Eng. Appl. Electrochem., 49, 336 (2013)

[15] Farfan EM, Sham E, Grange P, Catal. Today, 15, 515 (1992)

[16] Toranzo R, Vicente MA, Banares-Munoz MA, Gandia LM, Gil A, Micropor. Mesopor. Mater., 173, 173 (1998)

[17] Poyato J, Tobias MM, Trillo JM, Inorg. Chim. Acta, 14, 307 (1987)

[18] Occelli ML, Catal. Today, 2, 339 (1988)

[19] Zuo SF, Huang QQ, Li J, Zhou RX, Appl. Catal. B: Environ., 91(1-2), 204 (2009)

[20] Sanabria NR, Centeno MA, Molina R, Moreno S, Appl. Catal. A: Gen., 356(2), 243 (2009)

[21] Chen M, Fan L, Qi L, Luo X, Zhou R, Zheng X, Catal. Commun., 10, 838 (2009)

[22] Huang Q, Zuo S, Zhou R, Catal. Commun., 95, 327 (2010)

[23] Yin YG, Research methods of heterogeneous catalysts, chemical industry, Press, Beijing, 582 (1988)

[24] Awate SV, Waghmode SB, Agashe MS, Catal. Commun., 5, 407 (2004)

[25] Lambert J, Poncelet G, Top. Catal., 4, 43 (1997)

[26] Pinnavaia TJ, Tzou M, Landau SD, J. Am. Chem. Soc., 107, 4783 (1985)

[27] Cool P, Vansant EF, Mol. Sieves, 1, 265 (1998)

[28] Farfan-Torres EM, Sham E, Grange P, Catal. Today, 15, 515 (1992)

[29] Chae HJ, Nam IS, Ham SW, Hong SB, Catal. Today, 68(1-3), 31 (2001)

[30] Devlin H, Harris I, Ind. Eng. Chem. Fund, 23, 387 (1984)

[31] Carriazo JG, Molina R, Moreno S, Appl. Catal. A: Gen., 334(1-2), 168 (2008)

[32] Barrault J, Tatiboue M, Papayannakos N, Comptes Rendus de l’Academie des Sciences - Series IIC - Chemistry, 3, 777 (2000)