Equilibrium, kinetics and thermodynamic studies for the removal of organophosphorus pesticide using Amberlyst-15 resin: Quantitative analysis by liquid chromatography.mass spectrometry

Mu. Naushad; Z.A. ALOthman; M.R. Khan; N.J. ALQahtani; I.H. ALSohaimi

Journal of Industrial and Engineering Chemistry, Vol.20, No.6, 4393-4400, November, 2014

DOI10.1016/j.jiec.2014.02.006 Export Citation

Equilibrium, kinetics and thermodynamic studies for the removal of organophosphorus pesticide using Amberlyst-15 resin: Quantitative analysis by liquid chromatography.mass spectrometry

Mu. Naushad^{1, †}, Z.A. ALOthman¹, M.R. Khan¹, N.J. ALQahtani^{1, 2}, and I.H. ALSohaimi¹

¹Department of Chemistry, College of Science, Bld#5, King Saud University, Riyadh, Saudi Arabia
²King Abdul Aziz for Science and Technology, Riyadh, Saudi Arabia

E-mail:

In the present paper, Amberlyst-15 resin was used for the removal of malathion. Various experimental parameters such as effect of pH, contact time, resin dose, initial malathion concentration and temperature were studied to find the optimum conditions for malathion removal. The removal rate of malathion by Amberlyst-15 was rapid and equilibrium was established within 30 min. Kinetic studies showed better applicability for pseudo-second-order model and equilibrium data was best fitted to Freundlich isotherm model. The thermodynamic parameters showed that the adsorption of malathion was feasible, endothermic and spontaneous. The concentration of malathion was determined using ultra-performance liquid chromatography-tandem mass spectrometry.

Keywords:Amberlyst-15 resin;Adsorption;Malathion;Kinetic studies;UPLC-MS/MS

[References]

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UN/DESA, Changing Unsustainable Patterns of Consumption and Production, Johannesburg Plan on Implementation of the World summit on Sustainable Development, Johannesburg, 2002 (Chapter III).
Casarett LJ, Doull’s J, Toxicology, the Basic Science of Poisons, 6th ed., MacGrow Hill, NY, 2001.
Fukuto TR, Environ. Health Perspect., 87, 245 (1990)
Lintellman J, Katayama A, Kurihara N, Shore L, Wenzel A, Pure Appl. Chem., 75, 631 (2003)
Andersen HR, Vinggaard AM, Rasmussen T, Gjermandsen IM, Bonefeld-Jorgensen EC, Toxicol. Appl. Pharmacol., 179, 1 (2002)
Degen GH, Bolt HM, Int. Arch. Occup. Environ. Health, 73, 433 (2000)
Kojima H, Katsura E, Takeuchi S, Niiyama K, Kobayashi K, Environ. Health Perspect., 112, 524 (2004)
Li J, Li N, Ma M, Giesy JP, Wang Z, Toxicol. Lett., 183, 65 (2008)
Drinking Water Directive (DWD) of European Community, Council Directive 98/83/EC, 2007, July.
Senthilkumaar S, Krishna SK, Kalaamani P, Subburamaan CVN, Subramaniam G, Mod. Appl. Sci., 4, 67 (2010)
Mohamed KA, Basfar AA, Kahtani HAAL, Hamad KSAL, Radiat. Phys. Chem., 78, 994 (2009)
Saritha P, Aparna C, Himabindu V, Anjaneyulu Y, J. Hazard. Mater., 149(3), 609 (2007)
Murthy HMR, Manonmani HK, J. Hazard. Mater., 149(1), 18 (2007)
Aungpradit T, Sutthivaiyakit P, Martens D, Sutthivaiyakit S, Kettrup AAF, J. Hazard. Mater., 146(1-2), 204 (2007)
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Ahmad AL, Tan LS, Shukor SRA, J. Hazard. Mater., 151(1), 71 (2008)
Maldonado MI, Malato S, Perez-Estrada LA, Gernjak W, Oller I, Domenech X, Peral J, J. Hazard. Mater., 138(2), 363 (2006)
Naushad M, ALOthman ZA, Khan MR, Talanta, 115, 15 (2013)
Chang CF, Chang CY, Hsu KE, Lee SC, Holl W, J. Hazard. Mater., 155(1-2), 295 (2008)
Hamadi NK, Swaminathan S, Chen XD, J. Hazard. Mater., 112(1-2), 133 (2004)
Davies M, Infrared Spectroscopy and Molecular Structure, Elsevier Publishing Co, Amsterdam, The Netherlands, 1963p. 318.
Singare PU, Lokhande RS, Madyal RS, Open J. Phys. Chem., 1, 45 (2011)
Naushad M, Chem. Eng. J., 235, 100 (2014)
Lagergren S, Vetenskapsakademiens KS, Handlingar Band, 24, 1 (1898)
Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)
Malik PK, J. Hazard. Mater., 113, 81 (2004)
Rauf N, Tahir SS, Kang JH, Chang YS, Chem. Eng. J., 192, 369 (2012)
Gupta VK, Ali I, Water Res., 35, 33 (2001)
Gupta VK, Jain CK, Ali I, Chandra S, Agarwal S, Water Res., 36, 2483 (2002)
Pal OR, Vanjara AK, Sep. Purif. Technol., 24(1-2), 167 (2001)
Mahramanlioglu M, Kizilcikli I, Bicer IO, J. Fluor. Chem., 115, 41 (2002)
Naushad M, ALOthman ZA, Islam M, Int. J. Environ. Sci. Technol., 10, 567 (2013)
ALOthman ZA, Naushad M, Nilchi A, J. Inorg. Organomet. Polym., 21, 547 (2011)
Namasivayam C, Sangeetha D, Bioresour. Technol., 97(10), 1194 (2006)
Lin J, Zhan Y, Zhu Z, Colloids Surf. A: Physicochem. Eng. Asp., 384, 9 (2011)

[Referenced By]

[1] Tadeo JL, Analysis of Pesticides in Food and Environmental Samples, CRC Press, Boca Raton, 2008.

[2] Ignatowicz K, J. Hazard. Mater., 169(1-3), 953 (2009)

[3] Rekha SN, Naik R, Prasad, Chem. Health Saf., 13, 12 (2006)

[4] ICAR, Report of the Special Committee on Harmful Effects of Pesticides, ICAR, New Delhi, 1967p. 78.

[5] UN/DESA, Changing Unsustainable Patterns of Consumption and Production, Johannesburg Plan on Implementation of the World summit on Sustainable Development, Johannesburg, 2002 (Chapter III).

[6] Casarett LJ, Doull’s J, Toxicology, the Basic Science of Poisons, 6th ed., MacGrow Hill, NY, 2001.

[7] Fukuto TR, Environ. Health Perspect., 87, 245 (1990)

[8] Lintellman J, Katayama A, Kurihara N, Shore L, Wenzel A, Pure Appl. Chem., 75, 631 (2003)

[9] Andersen HR, Vinggaard AM, Rasmussen T, Gjermandsen IM, Bonefeld-Jorgensen EC, Toxicol. Appl. Pharmacol., 179, 1 (2002)

[10] Degen GH, Bolt HM, Int. Arch. Occup. Environ. Health, 73, 433 (2000)

[11] Kojima H, Katsura E, Takeuchi S, Niiyama K, Kobayashi K, Environ. Health Perspect., 112, 524 (2004)

[12] Li J, Li N, Ma M, Giesy JP, Wang Z, Toxicol. Lett., 183, 65 (2008)

[13] Drinking Water Directive (DWD) of European Community, Council Directive 98/83/EC, 2007, July.

[14] Senthilkumaar S, Krishna SK, Kalaamani P, Subburamaan CVN, Subramaniam G, Mod. Appl. Sci., 4, 67 (2010)

[15] Mohamed KA, Basfar AA, Kahtani HAAL, Hamad KSAL, Radiat. Phys. Chem., 78, 994 (2009)

[16] Saritha P, Aparna C, Himabindu V, Anjaneyulu Y, J. Hazard. Mater., 149(3), 609 (2007)

[17] Murthy HMR, Manonmani HK, J. Hazard. Mater., 149(1), 18 (2007)

[18] Aungpradit T, Sutthivaiyakit P, Martens D, Sutthivaiyakit S, Kettrup AAF, J. Hazard. Mater., 146(1-2), 204 (2007)

[19] Martin MMB, Perez JAS, Sanchez JLG, de Oca LM, Lopez JLC, Oller I, Rodriguez SM, J. Hazard. Mater., 155(1-2), 342 (2008)

[20] Ahmad AL, Tan LS, Shukor SRA, J. Hazard. Mater., 151(1), 71 (2008)

[21] Maldonado MI, Malato S, Perez-Estrada LA, Gernjak W, Oller I, Domenech X, Peral J, J. Hazard. Mater., 138(2), 363 (2006)

[22] Naushad M, ALOthman ZA, Khan MR, Talanta, 115, 15 (2013)

[23] Chang CF, Chang CY, Hsu KE, Lee SC, Holl W, J. Hazard. Mater., 155(1-2), 295 (2008)

[24] Hamadi NK, Swaminathan S, Chen XD, J. Hazard. Mater., 112(1-2), 133 (2004)

[25] Davies M, Infrared Spectroscopy and Molecular Structure, Elsevier Publishing Co, Amsterdam, The Netherlands, 1963p. 318.

[26] Singare PU, Lokhande RS, Madyal RS, Open J. Phys. Chem., 1, 45 (2011)

[27] Naushad M, Chem. Eng. J., 235, 100 (2014)

[28] Lagergren S, Vetenskapsakademiens KS, Handlingar Band, 24, 1 (1898)

[29] Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)

[30] Malik PK, J. Hazard. Mater., 113, 81 (2004)

[31] Rauf N, Tahir SS, Kang JH, Chang YS, Chem. Eng. J., 192, 369 (2012)

[32] Gupta VK, Ali I, Water Res., 35, 33 (2001)

[33] Gupta VK, Jain CK, Ali I, Chandra S, Agarwal S, Water Res., 36, 2483 (2002)

[34] Pal OR, Vanjara AK, Sep. Purif. Technol., 24(1-2), 167 (2001)

[35] Mahramanlioglu M, Kizilcikli I, Bicer IO, J. Fluor. Chem., 115, 41 (2002)

[36] Naushad M, ALOthman ZA, Islam M, Int. J. Environ. Sci. Technol., 10, 567 (2013)

[37] ALOthman ZA, Naushad M, Nilchi A, J. Inorg. Organomet. Polym., 21, 547 (2011)

[38] Namasivayam C, Sangeetha D, Bioresour. Technol., 97(10), 1194 (2006)

[39] Lin J, Zhan Y, Zhu Z, Colloids Surf. A: Physicochem. Eng. Asp., 384, 9 (2011)