화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.6, 4353-4362, November, 2014
DOI10.1016/j.jiec.2014.01.043  Export Citation
Sorption studies of manganese and cobalt from aqueous phase onto alginate beads and nano-graphite encapsulated alginate beads
Moonis Ali Khan, Woosik Jung1, Oh-Hun Kwon1, Young Mee Jung2, Ki-Jung Paeng3, Seung-Yeon Cho1, and Byong-Hun Jeon1, †
  • Advanced Materials Research Chair, Chemistry Department, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
  • 1Department of Environmental Engineering, Yonsei University, 1 Yonseidae-gil, Wonju 220-710, Republic of Korea
  • 2Department of Chemistry, Kangwon National University, 1 Kangwondaehak-gil, Chuncheon 200-701, Republic of Korea
  • 3Department of Chemistry, Yonsei University, 1 Yonsei dae-gil, Wonju 220-710, Republic of Korea
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Comparative sorption study of dissolved manganese and cobalt ions onto alginate beads (ABs) and thermally activated nano-carbon beads (NCBs) was performed. Acidic functionalities dominate over sorbent surface. Elemental analysis confirmed that divalent calciumreplacement with heavy metal ions might be a possible sorption mechanism. Optimum metal uptake was observed at pH 8. Most of the metal ions (80-92%) were sorbed within 4 h, followed by a slower sorption stage. Mn(II) and Co(II) recovery was greater than 99% with 0.1 N HCl, and NCB could be repeatedly utilized for Mn(II) and Co(II) sorption with negligible loss in sorption capacity.
Keywords:Nano-carbon beads;Thermal activation;Sorption;Desorption;Regeneration
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