Utilization of waste cation exchange resin to prepare carbon/iron composites for the adsorption of contaminants in water

Qianqian Shi; Aimin Li; Qing Zhou; Chendong Shuang; Yan Li; Yan Ma

Journal of Industrial and Engineering Chemistry, Vol.20, No.6, 4256-4260, November, 2014

DOI10.1016/j.jiec.2014.01.029 Export Citation

Utilization of waste cation exchange resin to prepare carbon/iron composites for the adsorption of contaminants in water

Qianqian Shi, Aimin Li^†, Qing Zhou, Chendong Shuang, Yan Li, and Yan Ma

State Key Laboratory of Pollution Control and Resources Reuse, School of the Environment, Nanjing University, Nanjing 210023, China

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Carbon/iron composites were prepared from waste cation exchange resin by NaOH activation. The BET surface areas were over 1200 m2 g-1. The presence of iron led to the formation of new mesopores and macropores. Activation temperature had a significant impact on the pore size distributions, crystal structures, and magnetic properties of the carbon composites, and the magnetic properties of the composites were related to their crystal structures. The composite synthesized at 800 ℃(800ACS-1) could effectively remove diethyl phthalate, bisphenol A, and malachite green from aqueous solutions. 800ACS-1 also exhibited high stability over a wide pH range of 4-11.5.

Keywords:Waste cation exchange resin;Carbon/iron composites;Activation temperature;Adsorption

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[2] Rengaraj S, Joo CK, Kim Y, Yi J, J. Hazard. Mater., 102(2-3), 257 (2003)

[3] Nakahiro Y, Horio U, Niinae M, Kusaka E, Wakamatsu T, Miner. Eng., 5, 1389 (1992)

[4] Vera E, Dornier M, Ruales J, Vaillant F, Reynes M, J. Food Eng., 57(2), 199 (2003)

[5] Chakrabarti A, Sharma MM, React. Polym., 20, 1 (1993)

[6] Global Industry Analysts, Inc., Ion exchange resins - a global strategic business report, http://www.strategyr.com/Ion_Exchange_Resins_Market_Report.asp.

[7] Gun’ko VM, Leboda R, Skubiszewska-Zieba J, Charmas B, Oleszczuk P, Carbon, 43, 1143 (2005)

[8] Bratek W, Bratek K, Kulazynski M, Fuel Process. Technol., 77-78, 431 (2002)

[9] Bratek K, Bratek W, Kulazynski M, Carbon, 40, 2213 (2002)

[10] Long C, Lu JD, Li AM, Hu DB, Liu FQ, Zhang QX, J. Hazard. Mater., 150, 656 (2008)

[11] Han SJ, Kim YH, Kim KS, Park SJ, Curr. Appl. Phys., 12(4), 1039 (2012)

[12] Rudge SR, Kurtz TL, Vessely CR, Catterall LG, Willamson DL, Biomaterials, 21, 1411 (2000)

[13] Yang M, Xie Q, Zhang J, Liu J, Wang Y, Zhang X, Zhang Q, Min. Sci. Technol., 20, 872 (2010)

[14] Yang N, Zhu S, Zhang D, Xu S, Mater. Lett., 62, 645 (2008)

[15] Thi DN, Ngoc HP, Manh HD, Kim TN, J. Hazard. Mater., 185(2-3), 653 (2011)

[16] Oliveira LCA, Rios RVRA, Fabris JD, Garg V, Sapag K, Lago RM, Carbon, 40, 2177 (2002)

[17] Daud WMAW, Ali WSW, Sulaiman MZ, J. Chem. Technol. Biotechnol., 78(1), 1 (2003)

[18] Lua AC, Yang T, J. Colloid Interface Sci., 274(2), 594 (2004)

[19] Li C, Wang X, Liu Y, Wang W, Wynn J, Gao J, J. Nanopart. Res., 14, 875 (2012)

[20] Han Q, Liu Z, Xu Y, Chen Z, Wang T, Zhang H, J. Phys. Chem. C, 111, 5034 (2007)

[21] Zhao F, Duan H, Wang W, Wang J, Physica B, 407, 2495 (2012)

[22] Faria PCC, Orfao JJM, Pereira MFR, Water Res., 38, 2043 (2004)

[23] Tan IAW, Ahmad AL, Hameed BH, J. Hazard. Mater., 154(1-3), 337 (2008)

[24] Medellin-Castillo NA, Ocampo-Perez R, Leyva-Ramos R, Sanchez-Polo M, Rivera-Utrilla J, Mendez-Diaz JD, Sci. Total Environ., 442, 26 (2013)

[25] de Oliveira TF, Cagnon B, Fauduet H, Licheron M, Chedeville O, Sep. Sci. Technol., 47(8), 1139 (2012)

[26] Bautista-Toledo I, Ferro-Garcia MA, Rivera-Utrilla J, Moreno-Castilla C, Fernandez FJV, Environ. Sci. Technol., 39, 6246 (2005)

[27] Chang KL, Hsieh JF, Ou BM, Chang MH, Hseih WY, Lin JH, Huang PJ, Wong KF, Chen ST, Sep. Sci. Technol., 47(10), 1514 (2012)

[28] Liu G, Ma J, Guan C, Li X, Qin Q, Li G, Environ. Sci., 29, 349 (2008)

[29] Hameed BH, El-Khaiary MI, J. Hazard. Mater., 157(2-3), 344 (2008)

[30] Ai LH, Huang HY, Chen ZL, Wei X, Jiang J, Chem. Eng. J., 156(2), 243 (2010)

[31] Basar CA, J. Hazard. Mater., 135(1-3), 232 (2006)

[32] Akmil-Basar C, Onal Y, Kilicer T, Eren D, J. Hazard. Mater., 127(1-3), 73 (2005)