Determination of gold and palladium in environmental samples by FAAS after dispersive liquid-liquid microextraction pretreatment

Coskun Ozdemir; Serife Sacmaci; Senol Kartal; Mustafa Sacmaci

Journal of Industrial and Engineering Chemistry, Vol.20, No.6, 4059-4065, November, 2014

DOI10.1016/j.jiec.2014.01.005 Export Citation

Determination of gold and palladium in environmental samples by FAAS after dispersive liquid-liquid microextraction pretreatment

Coskun Ozdemir, Serife Sacmaci^†, Senol Kartal, and Mustafa Sacmaci

Erciyes University, Department of Chemistry, Faculty of Sciences, TR-38039 Kayseri, Turkey

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A new dispersive liquid.liquid microextraction (DLLME) method is proposed for rapid separation, simultaneous extraction and preconcentration of gold and palladium at ultra trace amounts. The extraction of the analytes was performed in the presence of 5-[(E)-(2,6-diaminopyridine-3-yl)diazenyl]-1,3,4-thiadiazole-2-thiol (DAT) as chelating agent. Chloroform and acetone were used as extraction and dispersive solvents, respectively. The variables affecting the complexation and extraction conditions were optimized. The calibration curves were linear in the range of 1.1-85 and 0.9-124 μg L-1 with the detection limits of 0.4 and 0.6 μg L-1, and with the enrichment factors of 94 and 113 for Au and Pd, respectively. The precision (RSD%) was better than 2.4%. The accuracy of the method was verified by analysing the certified standard reference material (CDN-PGMS-10). The results show that the dispersive liquid.liquid microextraction pretreatment is a sensitive, rapid, simple and safe method for the separation/preconcentration of gold and palladium.

Keywords:Gold;Palladium;Dispersive liquid-liquid microextraction;Chelating agent;FAAS

[References]

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[Referenced By]

[1] Tavakoli L, Yamini Y, Ebrahimzadeh H, Nezhadali A, Shariati S, Nourmohammadian F, J. Hazard. Mater., 152(2), 737 (2008)

[2] EPOW-European Pathway to Zero Waste, Protecting and Recovering Critical Raw Materials, Oakdene Hollins Ltd., Aylesbury, England, hhttp://www.environmentagency.gov.uk/EPOWi accessed on January 21 (2014)

[3] Bruzzoniti MC, Mucchino C, Tarasco E, Sarzanini C, J. Chromatogr. A, 1007, 93 (2003)

[4] Amin AS, Spectrochim. Acta, Part A, 77, 1054 (2010)

[5] Ott I, Coord. Chem. Rev., 253, 1670 (2009)

[6] Afzali D, Mostafavi A, Mirzaei M, J. Hazard. Mater., 181(1-3), 957 (2010)

[7] Rancic SM, Nikolic-Mandic SD, Mandic LM, Anal. Chim. Acta, 547, 144 (2005)

[8] Motelica-Heino M, Rauch S, Morrison GM, Donard OFX, Anal. Chim. Acta, 436, 233 (2001)

[9] Manzoori JL, Sorouraddin MH, Hajishabani AM, Microchem. J., 63, 295 (1999)

[10] Manzoori JL, Sorouraddin MH, Hajishabani AM, J. Anal. At. Spectrom., 13, 305 (1998)

[11] Manzoori JL, Sorouraddin MH, Shemirani F, Anal. Lett., 29, 2007 (1996)

[12] Manzoori JL, Shemirani F, J. Anal. At. Spectrom., 10, 881 (1995)

[13] Pyrzynska K, Talanta, 47, 841 (1998)

[14] Daniel S, Babu PEJ, Rao TP, Talanta, 65, 441 (2005)

[15] Igarashi S, Ide N, Takagai Y, Anal. Chim. Acta, 424, 263 (2000)

[16] Hu Q, Yand X, Huang Z, Chen J, Yang G, J. Chromatogr. A, 1094, 77 (2005)

[17] Anthemidis AN, Themelis DG, Stratis JA, Talanta, 54, 37 (2001)

[18] Sacmacı S, Kartal S, Talanta, 109, 26 (2013)

[19] Sacmacı S, Kartal S, Dural S, J. Braz. Chem. Soc., 23, 1033 (2012)

[20] Wu HF, Kailasa SK, Yan JY, Chin CC, Ku HY, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.09.034, in press. (2013)

[21] Sacmacı S, Sahan S, Sacmacı M, Sahin U, Ulgen A, Kartal S, Int. J. Environ. Anal. Chem., 93(12), 1223 (2013)

[22] Pyrzynska K, Spectrochim. Acta, Part B, 60, 1316 (2005)

[23] Carasek E, Talanta, 51, 173 (2000)

[24] da Silva MAM, Frescura VLA, Crtius AJ, Spectrochim. Acta, Part B, 55, 803 (2000)

[25] Afzali D, Ghazizadeh A, Salari H, Quim. Nova, 34, 1124 (2011)

[26] Bagheri M, Mashhadizadeh MH, Razee S, Talanta, 60, 839 (2003)

[27] Behbahani M, Najafi F, Amini MM, Sadeghi O, Bagheri A, Hassanlou PG, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.09.057, in press. (2013)

[28] Ghaedi M, Ghayedi M, Kokhdan SN, Sahraei R, Daneshfar A, J. Ind. Eng. Chem., 19(4), 1209 (2013)

[29] Kiziroglou ME, Mukherjee AG, Moseley RW, Taylor P, Pranonsatita S, Holmesa AS, Yeatmana EM, Proc. SPIE 6882 68820B-9.

[30] Whiteley JD, Murray F, Geochem. Explor. Environ. Anal., 5, 3 (2005)

[31] da Silva MAM, Frescura VLA, Curtius AJ, Spectrochim. Acta, Part B, 56, 1941 (2001)

[32] Miro M, Estela JM, Cerda V, Curr. Anal. Chem., 1, 329 (2005)

[33] Pereira FP, Lavilla I, Bendicho C, Spectrochim. Acta, Part B, 64, 1 (2009)

[34] Anthemidis AN, Adam ISI, Anal. Chim. Acta, 632, 216 (2009)

[35] Adam ISI, Anthemidis AN, Talanta, 77, 1160 (2009)

[36] Paleologos EK, Giokas DL, Karayannis MI, Trends Anal. Chem., 24, 426 (2005)

[37] Razaee M, Assadi Y, Hosseini MRM, Aghaee E, Ahmadia F, Berijani S, J. Chromatogr. A, 1116, 1 (2006)

[38] Anthemidis AN, Ioannou KIG, Talanta, 79, 86 (2009)

[39] Jahromi EZ, Bidari A, Assadi Y, Hosseini MRM, Jamali MR, Anal. Chim. Acta, 585, 305 (2007)

[40] Elci L, Kartal S, Ulgen A, Dogan M, Dogan P, Turk. J. Chem., 14, 294 (1990)

[41] Zhang S, Pu Q, Liu P, Sun Q, Su Z, Anal. Chim. Acta, 452, 223 (2002)

[42] Liang P, Zhao E, Ding Q, Du D, Spectrochim. Acta, Part B, 63, 714 (2008)

[43] Ashkenani H, Taher MA, Microchem. J., 103, 185 (2012)

[44] Ebrahimzadeh H, Tavassoli N, Amini MM, Fazaeli Y, Abedi H, Talanta, 81, 1183 (2010)

[45] Ebrahimzadeh H, Moazzen E, Amini MM, Sadeghi O, Chem. Eng. J., 215, 315 (2013)

[46] Shamsipur M, Ramezani M, Talanta, 75, 294 (2008)