화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.31, No.12, 2286-2290, December, 2014
DOI10.1007/s11814-014-0143-y  Export Citation
One-pot synthesis of 5-hydroxymethylfurfural directly from cottonseed hull biomass using chromium (III) chloride in ionic liquid
Shui Wang, Yizhen Du, Ping Zhang, Xiaowei Cheng, and Yixin Qu†
  • Beijing Key Laboratory of Membrane Science and Technology, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
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We studied the direct synthesis of 5-hydroxymethylfurfural (5-HMF) from cottonseed hull biomass under acid condition in one-pot. The influence of HCl dosage, reaction temperature and time, CrCl3·6H2O amount, and cottonseed hull loading on the yield of 5-HMF was investigated. As a result, a 5-HMF yield up to 51% was obtained using 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) catalyzed with chromium (III) chloride at 130 ℃ for 2 h. The [Bmim]Cl/ CrCl3·6H2O/HCl system was found to have high activity and selectivity for the dehydration of cellulose into 5-hydroxymethylfurfural. This work provides a low cost, environment-friendly and energy-efficient process to directly convert raw biomass into bio-fuels and chemicals.
Keywords:Cottonseed Hull;5-Hydroxymethylfurfural;Furfural;Chromium (III) Chloride;[BMIM]Cl
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