화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.31, No.12, 2124-2129, December, 2014
DOI10.1007/s11814-014-0322-x  Export Citation
Characterizations of furfuryl alcohol oligomer/polymerization catalyzed by homogeneous and heterogeneous acid catalysts
Taejin Kim1, 2, †, Jiwon Jeong3, Mohammed Rahman1, Elaine Zhu1, and Devinder Mahajan1, 2
  • 1Chemical and Molecular Engineering Department, Stony Brook University, Stony Brook, NY 11794, USA
  • 2Materials Science and Engineering Department, Stony Brook University, Stony Brook, NY 11794, USA
  • 3Chemistry Department, Stony Brook University, Stony Brook, NY 11794, USA
E-mail:
The liquid-phase oligomer/polymerization of furfuryl alcohol (FA) catalyzed by homogeneous and heterogeneous acid catalysts was investigated by Infrared (IR) spectroscopy. At room temperature and 100 ℃, FA was not decomposed with metal oxide catalysts except for tungsten oxide, whereas amberlyst and sulfuric acid converted a furfuryl alcohol monomer into oligomer/polymer even at a room temperature. During FA oligomer/polymerization reaction, a strong C=O band observed in the IR spectra provided a diketone structure, which was not observed in the Raman spectroscopy. Based on the FA monomer color changings and IR spectra, tungsten oxide can be possibly applied as a heterogeneous catalyst for controlling the product distribution and avoiding a product separation issue from catalyst.
Keywords:Furfuryl Alcohol;Oligomer/Polymerization;Metal Oxide;Heterogeneous;Homogeneous;Infrared Spectroscopy
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