화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.31, No.11, 2014-2019, November, 2014
Investigation of photocatalytic degradation of clindamycin antibiotic by using nano-ZnO catalysts
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The photocatalytic degradation of clindamycin (CLM) was studied by a batch reactor using UV irradiation and ZnO catalyst. The effects of several parameters such as pH, catalyst loading, light intensity and irradiation time were evaluated in the removal process. The results showed that the degradation of CLM was effective in alkaline conditions. The optimum catalyst loading in an aqueous solution containing 25 mM of CLM and UV lamp of 50 W was observed at 3.0 g/L of catalyst loading. The process followed pseudo-first order kinetics, and the apparent rate constant (k) decreased with increasing the initial concentration of CLM. The photocatalytic process had higher removal efficiency in synthetic than actual wastewater in optimum conditions.
  1. Kummerer K, J. Antimicrob. Chemother., 52, 5 (2003)
  2. Morar M, Bhullar K, Hughes DW, Junop M, Wright GD, Structure, 17, 1649 (2009)
  3. Zhu A, Zhu W, Wu Z, Jing Y, Water Res., 37, 3718 (2003)
  4. Rahmani H, Gholami M, Mahvi A, Alimohammadi M, Azarian G, Esrafili A, Rahmani K, Farzadkia M, Bull. Environ. Contam. Toxicol., 1 (2014)
  5. Kansal SK, Singh M, Sud D, Chem. Eng. Commun., 194(6), 787 (2007)
  6. Kansal SK, Singh M, Sud D, Desalination, 228(1-3), 183 (2008)
  7. Kusvuran E, Samil A, Atanur OM, Erbatur O, Appl. Catal. B: Environ., 58(3-4), 211 (2005)
  8. Neppolian B, Choi HC, Sakthivel S, Arabindoo B, Murugesan V, J. Hazard. Mater., 89(2-3), 303 (2002)
  9. Eslami A, Nasseri S, Yadollahi B, Mesdaghinia A, Vaezi F, Nabizadeh R, Nazmara S, J. Chem. Technol. Biotechnol., 83(11), 1447 (2008)
  10. Kansal SK, Singh M, Sud D, J. Hazard. Mater., 141(3), 581 (2007)
  11. Lizama C, Freer J, Baeza J, Mansilla WD, Catal. Today, 76(2-4), 235 (2002)
  12. Lathasree S, Rao AN, SivaSankar B, Sadasivam V, Rengaraj K, J. Mol. Catal. A-Chem., 223(1-2), 101 (2004)
  13. Curri M, Comparelli R, Cozzoli P, Mascolo G, Agostiano A, Mater. Sci. Eng.: C, 23, 285 (2003)
  14. Kamat PV, Huehn R, Nicolaescu R, J. Phys. Chem. B, 106(4), 788 (2002)
  15. Moshfegh A, J. Phys. D: Appl. Phys., 42, 233001 (2009)
  16. Zhang H, Chen G, Bahnemann DW, J. Mater. Chem., 19, 5089 (2009)
  17. Elmolla ES, Chaudhuri M, J. Hazard. Mater., 173(1-3), 445 (2010)
  18. Mekasuwandumrong O, Pawinrat P, Praserthdam P, Panpranot J, Chem. Eng. J., 164(1), 77 (2010)
  19. Byrappa K, Subramani A, Ananda S, Rai KL, Dinesh R, Yoshimura M, Bull. Mater. Sci., 29, 433 (2006)
  20. Farzadkia M, Esrafili A, Baghapour MA, Shahamat YD, Okhovat N, Des. Water Treat., 1 (2013)
  21. Murov SL, Carmichael I, Hug GL, Handbook of photochemistry, CRC Press, New York, Basel (1993)
  22. Corporation PE, Analytical methods for atomic absorption spectrophotometry (1964)
  23. Awwa A, Washington, DC Standard Methods for the Examination of Water and Wastewater, 20 (1998)
  24. Samah M, Merabet S, Bouguerra M, Bouhelassa M, Ouhenia S, Bouzaza A, Kinet. Catal., 52, 34 (2011)
  25. Jafari AJ, Kalantari RR, Gholami M, Iran. J. Healt. Environ., 5 (2012)
  26. Moreno-Castilla C, Carbon, 42, 83 (2004)
  27. Menendez J, Illan-Gomez M, Radovic L, Carbon, 33, 1655 (1995)
  28. Kikuchi Y, Qian Q, Machida M, Tatsumoto H, Carbon, 44, 195 (2006)
  29. Kansal SK, Ali AH, Kapoor S, Desalination, 259(1-3), 147 (2010)
  30. Hameed B, Akpan U, Wee KP, Des. Water Treat., 27, 204 (2011)
  31. Zhou L, Guo W, Xie G, Feng J, Des. Water Treat., 1 (2013)
  32. Kansal SK, Kaur N, Singh S, Nanoscale. Res. Lett., 4, 709 (2009)
  33. Chen C, Liu J, Liu P, Yu B, Adv. Chem. Eng. Sci., 1, 9 (2011)
  34. Liu YM, Hua L, Li SQ, Desalination, 258(1-3), 48 (2010)
  35. Rao AN, Sivasankar B, Sadasivam V, J. Hazard. Mater., 166(2-3), 1357 (2009)
  36. Pardeshi SK, Patil AB, J. Hazard. Mater., 163(1), 403 (2009)