화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.31, No.11, 1973-1979, November, 2014
DOI10.1007/s11814-014-0148-6  Export Citation
The effects of MCM-41’s calcination temperature on the structure and hydrodenitrogenation over NiW catalysts
Fang Guo1, 2, Shaoqing Guo3, Xian-Xian Wei1, 2, Xiaoxiao Wang3, Hongwei Xiang1, Zegang Qiu1, †, and Liangfu Zhao1, †
  • 1Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China
  • 2Graduate University of the Chinese Academy of Sciences, Beijing 100039, P. R. China
  • 3Taiyuan University of Science and Technology, Taiyuan 030024, P. R. China
E-mail:,
MCM-41 was calcined at 500, 560, 600 or 650 ℃. It was used as support for NiW catalysts of hydrodenitrogenation (HDN) for quinoline in order to investigate the influences of the MCM-41’s calcination temperature on the structure and the HDN performance of NiW catalysts. The NiW catalysts were characterized by XRD, N2 adsorptiondesorption, XPS, Raman, HRTEM and Py-IR techniques. The results showed that the surface area (SBET), the average pore diameter (Dp) and the pore volume (Vp) of the MCM-41 increased with increase of the MCM-41’s calcination temperature. The high SBET, Dp and Vp were beneficial for the high dispersion of W species, the formation of appropriate nature of W species and acid sites on the catalysts. The HDN activity followed the order of NiW-650≒NiW-600>NiW- 560>NiW-500, while the relative selectivity of HDN pathways was similar for all the catalysts.
Keywords:NiW Catalysts;Calcination Temperature;Hydrodenitrogenation;Quinoline
  1. Dominguez-Crespo MA, Torres-Huerta AM, Diaz-Garcia L, Arce-Estrada EM, Ramirez-Meneses E, Fuel Process. Technol., 89(8), 788 (2008)
  2. Soni KK, Mouli KC, Dalai AK, Adiaye J, Micropor. Mesopor. Mater., 152, 224 (2012)
  3. Peeters E, Cattenot M, Geantet C, Breysse M, Zotin JL, Catal. Today, 133, 299 (2008)
  4. Luan YZ, Zhang QM, He DM, Guan J, Liang CH, Asia-Pac. J. Chen. Eng., 4, 704 (2009)
  5. Al-Megren HA, Gonzalez-Cortes SL, Xiao T, Green MLH, Appl. Catal. A: Gen., 329, 36 (2007)
  6. Cui GQ, Wang JF, Fan HF, Sun XY, Jiang Y, Wang SJ, Liu D, Gui JZ, Fuel Process. Technol., 92(12), 2320 (2011)
  7. Li SZ, Lee JS, J. Catal., 173(1), 134 (1998)
  8. Clark P, Li W, Oyama ST, J. Catal., 200(1), 140 (2001)
  9. Fan Y, Bao XJ, Wang H, Chen CF, Shi G, J. Catal., 245(2), 477 (2007)
  10. Guemez MB, Canbra JF, Arias PL, Legarreta JA, Fierro JLG, Fuel, 74, 285 (1995)
  11. Duan XP, Li X, Wang AJ, Teng Y, Wang Y, Hu YK, Catal. Today, 149(1-2), 11 (2010)
  12. Lu MH, Wang AJ, Li X, Duan XP, Teng Y, Wang Y, Song CS, Hu YK, Energy Fuels, 21(2), 554 (2007)
  13. Basha SJS, Vijayan P, Suresh C, Santhanaraj D, Shanthi K, Ind. Eng. Chem. Res., 48(6), 2774 (2009)
  14. Basha SJS, Sasirekha NR, Maheswari R, Shanthi K, Appl. Catal. A: Gen., 308, 91 (2006)
  15. Khder AS, Hassan HMA, El-Shall MS, Appl. Catal. A: Gen., 411, 77 (2012)
  16. Chen CY, Li HX, Davis ME, Microporous Mater., 2, 17 (1993)
  17. Keene MTJ, Gougeon RDM, Denoyel R, Harris RK, Rouquerol J, Llewellyn PL, J. Mater. Chem., 9, 2843 (1999)
  18. Vetrivel S, Pandurangan A, J. Mol. Catal. A-Chem., 227(1-2), 269 (2005)
  19. Kraleva E, Saladino ML, Spinella A, Nasillo G, Caponetti E, J. Mater. Sci., 46(22), 7114 (2011)
  20. Soni K, Boahene PE, Mouli KC, Dalai AK, Adjaye J, Appl. Catal. A: Gen., 398(1-2), 27 (2011)
  21. Vradman L, Landau MV, Kantorovich D, Koltypin Y, Gedaken A, Microporous Mesoporous Mater., 79, 307 (2005)
  22. Luo YM, Hou ZY, Li RT, Zheng XM, Microporous Mesoporous, 109, 585 (2008)
  23. Vradman L, Landau MV, Herskowitz M, Ezersky V, Talianker M, Nikitenko S, Koltypin Y, Gedanken A, J. Catal., 213(2), 163 (2003)
  24. Lee JJ, Kim H, Koh JH, Jo A, Moon SH, Appl. Catal. B: Environ., 58(1-2), 89 (2005)
  25. Lawrence SJ, Makovsky LE, Stencel JE, Brown FR, Hercules DM, J. Phys. Chem., 85, 3700 (1981)
  26. Chen H, Dai WL, Deng JF, Fan KN, Catal. Lett., 81(1-2), 131 (2002)
  27. Kim DS, Ostromecki M, Wachs IE, Catal. Lett., 33(3-4), 209 (1995)
  28. Lei ZP, Gao LJ, Shui HF, Chen WL, Wang ZC, Ren SB, Fuel Process. Technol., 92(10), 2055 (2011)
  29. Kalita P, Gupta NM, Kumar R, J. Catal., 245(2), 338 (2007)
  30. Sursh C, Santhanaraj D, Gurulakshmi M, Deepa G, Selvaraj M, Rekha NRS, Shanthi K, ACS Catal., 2, 127 (2012)
  31. Li X, Wang AJ, Sun ZC, Li C, Ren J, Zhao B, Wang Y, Chen YY, Hu YK, Appl. Catal. A: Gen., 254(2), 319 (2003)
  32. Jian M, Prins R, J. Catal., 179(1), 18 (1998)
  33. Prins R, Jian M, Flechsenhar M, Polyhedron, 16, 3235 (1997)
  34. Cocchetto JF, Satterfield CN, Ind. Eng. Chem. Process. Des., 20, 49 (1981)