Thin Solid Films, Vol.554, 209-212, 2014
Continuous-wave photoinduced absorption study on trapped carriers in bulk-heterojunction solar cells connected to load
By using continuous-wave photoinduced absorption spectroscopy, we investigate hole-transport processes in polymer-based bulk-heterojunction solar cells at various operating points between the open- and short-circuit conditions. The results reveal that the detrapping time constant of holes decreases as the short-circuit condition is approached. This decrease may be explained by an acceleration of detrapping that is caused by an internal electric field. This interpretation is supported by a numerical simulation based on rate equations, considering a low density of a single trap level. Since the detrapping signal disappears at short-circuit, we estimate the associated trap levels to be relatively shallow. (C) 2013 Elsevier B.V. All rights reserved.
Keywords:Bulk-heterojunction solar cells;Trap;Operating points;Photoinduced absorption spectroscopy;Carrier transport