Thin Solid Films, Vol.534, 566-571, 2013
Nano-precipitates induced room temperature ferromagnetism in heavily Nb-doped titania thin films
Room temperature ferromagnetism (FM) is observed for annealed heavily niobium doped titania (TNO) thin films on silicon substrates and on glass nanospheres. Precipitation of similar to 10-30 nm-diameter Nb2O5 nanoparticles occurs in the TNO films air-annealed at 600 degrees C or above and enhances their saturation magnetization (M-s). The largest M-s is found in the 800 degrees C annealed 40 nm-thick TNO films on glass nanospheres (similar to 6 x 10(4) A/m) and the Ms reduces as films increased in thickness or deposited on flat Si substrates or annealed at lower temperature or in hydrogen. This work demonstrates that nano-precipitates and interfaces are both significant factors in achieving enhanced FM in the titania based thin films. (C) 2013 Elsevier B.V. All rights reserved.