화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 3524-3535, September, 2014
DOI10.1016/j.jiec.2013.12.045  Export Citation
Inhibition of mild steel corrosion in acidic medium by some cationic surfactants
Ismail Aiad, Mohamed M. El-Sukkary, E.A. Soliman, Moshira Y. El-Awady, and Samy M. Shaban†
  • Petrochemical Department, Egyptian Petroleum Research Institute, Faculty of Science, Ain Shams University, Cairo, Egypt
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The inhibition effect of some cationic surfactants on the corrosion of mild steel in 1.0 M HCl solution was studied by weight loss at 25-70 ℃ while potentiodynamic polarization and electrochemical impedance were used at 25 ℃. The results showed that all synthesized inhibitors were good inhibitors and their inhibition efficiencies were significantly increased by increasing both the concentration and temperature. Polarization curves revealed that the studied inhibitors act as mixed-type of inhibitors. Double-layer capacitances decrease with respect to the blank solution when these inhibitors added due to adsorption of these inhibitors on the steel surface. The adsorption of these inhibitors was found to obey Villamil adsorption model.
Keywords:Steel;Weight loss;Potentiodynamic polarization;Impedance;Adsorption isotherm.
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