화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 3342-3348, September, 2014
DOI10.1016/j.jiec.2013.12.018  Export Citation
Synthesis, characterization and surface properties of amino-glycopolysiloxane
M.M.A. EL-Sukkary†, D.A. Ismail, S.M.El. Rayes1, and M.A. Saad1
  • Petrochemicals, Egyptian Petroleum Research Institute, Cairo, Egypt
  • 1Organic Chemistry, Suez Canal University, Ismailia, Egypt
E-mail:
Three series of amino-grafted polysiloxane surfactants with well-defined amphiphilic structures, were successfully synthesized and characterized by FT-IR and 1H NMR. Their surface activities and aggregation behavior in aqueous solution were investigated by surface tension measurements for different concentrations at 25 ℃. Various surface properties of the synthesized surfactants, particularly interfacial tension, foaming power, emulsification power and surface parameters like, critical micelle concentration (CMC), effectiveness (pCMC), efficiency (PC20) as well as maximum surface excess (Gmax) and minimum surface area (Amin) were evaluated. Micellization and adsorption in liquid/air interfaces thermodynamics were investigated. All compounds prepared showed good surface properties, surface parameters and thermodynamic parameters.
Keywords:Amino glycoopolysiloxane surfactants;Surface tension measurements;Amphiphilic;Surface activity
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