The ACRPAC (Analysis of Capillary Rise Profile Around a Cylinder) method was modified and extended to measure the contact angles between an oil-water interface and a fiber. Basically, the accurate image of the partial capillary depression profile was acquired and digitized by applying computer digital image processing and analysis techniques. The contact angle was determined by finding the best fit of the theoretically predicted profile, i.e., the curve representing a solution of the Laplace equation of capillarity, to the physically observed liquid-liquid interface. This analysis of the capillary depression profile around a cylinder (ACDPAC) technique was used to measure the contact angles of different water-oil interfaces on cylindrical glass fibers pre-coated with FC725. The wettability of the fiber-water-oil systems with varying oil and aqueous phases was examined. In particular, the wetting effects of a cationic surfactant cetyltrimethylammonium bromide (CTAB) and an anionic surfactant sodium dodecyl sulfate (SDS) dissolved in the aqueous phase were studied by using the ACDPAC technique. The oil phases tested were two dimethyl siloxane liquids, silicone oil A-type and silicone oil B-type.