화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.103, 171-183, 2012
Symmetry considerations in the empirical k.p Hamiltonian for the study of intermediate band solar cells
With the purpose of assessing the absorption coefficients of quantum dot solar cells, symmetry considerations are introduced into a Hamiltonian whose eigenvalues are empirical. In this way, the proper transformation from the Hamiltonian's diagonalized form to the form that relates it with Gamma-point exact solutions through k.p envelope functions is built accounting for symmetry. Forbidden transitions are thus determined reducing the calculation burden and permitting a thoughtful discussion of the possible options for this transformation. The agreement of this model with the measured external quantum efficiency of a prototype solar cell is found to be excellent. (c) 2012 Elsevier B.V. All rights reserved.