Journal of Colloid and Interface Science, Vol.195, No.1, 42-50, 1997
Pattern formation in spontaneous dewetting of thin apolar films
Various stages of evolution of surface instability leading to dewetting are investigated for thin (<100 nm) fluid films subjected to the long range van der Waals interactions on a nonwettable solid. The problems of pattern selection and complete three-dimensional morphology are resolved based on numerical solutions of the nonlinear two-dimensional thin film equation. The initial small scale random nonhomogeneities are quickly reorganized into a large scale coherent bicontinuous structure consisting of "hills" and "valleys," which is reminiscent of the classical picture of the spinodal decomposition in the linear approximation. On the level of a "unit-cell," the bicontinuous structure slowly evolves into an increasingly axisymmetric circular pattern, and eventually a growing circular hole (dry spot) is formed. Scaling arguments, as cell as the simulations give the characteristic mean area of a unit-cell containing a single hole to be proportional to (h(0)(4) gamma/\S\), where h(0) is mean thickness, gamma is surface tension, and S is the spreading coefficient.
Keywords:POLYMER-FILMS;LIQUID-FILMS;MACROSCOPIC PARAMETERS;NONLINEAR STABILITY;FOAM FILMS;RUPTURE;INSTABILITY;DRAINAGE;SYSTEMS