This work presents a boundary layer analysis for the free convection heat transfer from a vertical cylinder in bidisperse porous media with constant wall temperature. A boundary layer analysis and the two-velocity two-temperature formulation are used to derive the nonsimilar governing equations. The transformed governing equations are solved by the cubic spline collocation method to yield computationally efficient numerical solutions. The effects of inter-phase heat transfer parameter, modified thermal conductivity ratio, and permeability ratio on the heat transfer and flow characteristics are studied. Results show that an increase in the modified thermal conductivity ratio and the permeability ratio can effectively enhance the free convection heat transfer of the vertical cylinder in a bidisperse porous medium. Moreover, the thermal nonequilibrium effects are strong for low values of the inter-phase heat transfer parameter.