화학공학소재연구정보센터
Separation and Purification Technology, Vol.132, 736-743, 2014
Parameter study on the adsorptive drying of isopropanol in a fixed bed adsorber
This work focuses on the influence of process parameters on the dynamics of adsorptive water removal from polar organic solvents in a fixed bed adsorber. As a model solvent isopropanol with water concentrations between 5 and 4000 ppm(w) was used. In a first step equilibrium loadings on 3A and 4A zeolites were determined by shaker bottle experiments. The results were fitted to the Langmuir equation. In a second step fixed bed experiments were carried out in order to characterize the dynamic behavior of the adsorption process. In these experiments 3A zeolite shows a better drying performance than 4A zeolite. The breakthrough curves (BTC) could be well described by dynamic simulations using a set of differential equations for the mass balances and a linear driving force approach (LDF) for the kinetics. Pore diffusivities in the order of 10(-12) m(2)/s were obtained by the simulation, indicating that surface diffusion in the pores of the zeolites is the predominant mechanism of mass transfer. (C) 2014 Elsevier B.V. All rights reserved.