A series of MCM-41 mesoporous molecular sieves with different Si/Al molar ratio has been synthesized by hydrothermal crystalline method using cetyltrimethylammonium bromide as structural template, sodium silicate as silica source and sodium aluminate as aluminum source in alkaline solution. The results show that all the samples have hexagonal mesoporous structure. The secondary restructured materials exhibit well defined structure and the long distance order of the mesopores. The mesoporous structure for Si/Al=25 MCM-41 with high specific area can be maintained after hydrothermal stability test in boiling water more than 12 h, showing that the secondary restructure can enhance the hydrothermal stability of MCM-41 with the pore diameter size of larger than 3.3 nm and BET surface area of more than 800 m(2).g(-1). Furthermore, MCM-41 with Si/Al=25 has the optimal hydrothermal stability due to the introduction of Al atom. (c) 2012 Elsevier B.V. All rights reserved.