Li4Ti5O12/C composite anode materials were synthesized by a simple starch sot assisted method using TiO2-anatase and Li2CO3 as raw materials and soluble starch as carbon source. The influences of calcination temperature and starch amounts on the microstructure and electrochemical performance were systematically investigated. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and constant-current charge/discharge cycling tests. The results showed that the Li4Ti5O12/C composite with 10 wt.% starch synthesized at 800 degrees C for 6 h had homogeneous particle size distribution with an average particle size of 200-300 nm and exhibited the optimal electrochemical performance with specific discharge capacities of 168.5, 160.8, 155.1 and 141.8 mAh g(-1) at 0.2 degrees C. 1 degrees C. 2 degrees C and 5 degrees C rates, respectively, and satisfactory cycling stability. It could be attributed to the homogeneous ultrafine particles and in situ carbon coating, which enhanced the electronic conductivity and diffusion of lithium ions in the electrode. (C) 2011 Elsevier B.V. All rights reserved.