Journal of Industrial and Engineering Chemistry, Vol.3, No.2, 85-92, June, 1997
Reforming of Carbon Dioxide by Methane over Ni/TiO2 Catalysts
Reforming of carbon dioxide by methane was studied over Ni(10wt%)/TiO2 catalyst in a fixed bed flow reactor at atmospheric condition. The optimal conditions of calcination temperature, reduction temperature, and :he au:ount of Ni loading based on the catalytic activity are 550℃, 550℃, and 10wt%, respectively. Most of NiO phase peaks before reduction turn into Ni2+ions after reduction. The effect of promoters on the catalytic activity was investigated as follows Ca> Mg> K> Na. Adding alkali metal salts and alkali earth metals oxide to the catalyst could be inferred to increase the yield of carbon monoxide, and to remove carbon on catalyst surface resulted from reverse Boudouard reaction. The reverse water gas shift reaction also occurred depending upon the reaction condition.
- Edwards JH, Catal. Today, 23(1), 59 (1995)
- Gerlach T, Nature, 351(30), 352 (1991)
- Erdohelyi A, Cserenyi J, Papp E, Solymosi F, Appl. Catal. A: Gen., 108(2), 205 (1994)
- Gadalla AM, Bower B, Chem. Eng. Sci., 43(11), 3049 (1988)
- Park SE, Chang JS, Lee KW, Chem. Ind. Technol., 12(1), 17 (1994)
- Tang SB, Qiu FL, Lu SJ, Catal. Today, 24(3), 253 (1995)
- Vernon PDF, Green MLH, Cheethan AK, Ashcroft AT, Catal. Today, 13, 417 (1992)
- Takano A, Tagawa T, Goto S, J. Chem. Eng. Jpn., 27(6), 727 (1994)
- Richardson JT, Paripatyadar SA, Appl. Catal. A: Gen., 61, 293 (1990)
- Pae YI, Doh IJ, Sohn JR, J. Korean Ind. Eng. Chem., 6(6), 1170 (1995)
- Espinos JP, Gonzalez-Elipe AR, Caballero A, Garcia J, Munuzra G, J. Catal., 136, 415 (1992)
- Stiles AB, Catalyst Supports and Supported Catalysts, 68, Butterworth (1987)
- Tanabe K, Misono M, Ono Y, Hattori H, New Solid Acids and Bases, 47-51, Elsevier (1989)
- Chang JS, Park MS, Park SE, lee KW, Chon H, Theor. Appl. Chem. Eng., 1, 1095 (1995)
- Tanaka T, Kumagai H, Hattori H, Kudo M, Hasegawa S, J. Catal., 127, 221 (1991)