Structural, dielectric and ferroelectric properties of bismuth titanate (Bi4Ti3O12) obtained by solution combustion technique using dextrose as fuel is studied extensively in this paper. Dextrose is used as fuel as it has high reducing valancy and generates more number of moles of gases during the reaction. X-ray diffraction studies show that phase formation and crystallinity was reached only after calcinations at 800 C. Dielectric constant versus temperature curve shows ferroelectric to paraelectric transition temperature (T-c) to be 650 degrees C. The dielectric loss is very less (tan delta < 1) at lower temperatures but increases around 71 due to structural changes in the sample. Complex impedance curves show deviation from Debye behavior. The material shows a thin PE Loop with low remnant polarization due to high conductivity in the as prepared sample. (C) 2013 Elsevier Ltd. All rights reserved.