We report in-situ synthesis and direct deposition of Fe2O3 nanoparticles (NPs) on the ionic liquid (IL)-functionalized carbon nanotubes (fCNT). As shown in transmission electron microscope (TEM) and scanning TEM (STEM) images, Fe2O3 NPs with the diameter of 3-5 nm are randomly distributed on the sidewall of fCNT, revealing the nanocrystalline structure. The chemical identity and interaction of the fCNT/Fe2O3 composite are investigated by FT-IR, Raman and XPS analyses. In particular, the fCNT/Fe2O3 composite is solution-processable in a form of binder free and self-standing film. Such a free-standing electrode film based on the fCNT/Fe2O3 composite achieve the discharge capacity of 413 mAh g(-1) which is much greater than 34 mAh g(-1) of the CNT and 191 mAh g(-1) of the fCNT due to the redox reaction of Fe2O3 NPs. Moreover, the fCNT/Fe2O3 composite show the coulombic efficiency of 98% and the capacity fading from 272 mAh g(-1) to 182 mAh g(-1) after 50 cycles of charge/discharge. (C) 2014 Elsevier B.V. All rights reserved.