Journal of Chemical Thermodynamics, Vol.28, No.4, 433-446, 1996
Densities of (Water Plus Carbon-Dioxide) in the Temperature-Range 415 K to 700 K and Pressures Up to 35 MPa
New measurements of the amount-of-substance density of 11 mixtures of (water + carbon dioxide) are reported in the temperature range 415 K to 700 K at pressures from 6 MPa to 35 MPa. The results have been obtained using a fully-automated isochoric instrument. The average uncertainty of the density is estimated to be about +/-0.08 per cent for the mixture with the lowest water content, and +/-0.14 per cent for the mixture with the highest water content. Comparisons with independent sources of experimental data through a model based upon the two-fluid corresponding states principle are presented. The dew points of the mixtures studied have also been determined and are compared with values from the Peng-Robinson equation of state.
Keywords:PARTIAL MOLAR VOLUMES;SUPERCRITICAL CONDITIONS;INFINITE DILUTION;CO2;X-LESS-THAN-0.014;XCO2+(1-X)H2O;MIXTURES;NITROGEN