High surface area mesoporous polyaniline (M-PANI) films can be produced on the surface of glassy carbon electrodes by the electrochemical polymerization from a composite made by mixing a Brij 98 surfactant with a water solution of aniline and sulfuric acid. The surfactant serves as a structure directing agent. When the quantity of Brij 98 in the composite was 45% by weight, it formed a hexagonal phase that comprises a template of cylinders arranged on a hexagonal lattice with a hydrophilic core. The aniline monomer infiltrated the core of the templates. When the potential of the glassy carbon electrode was cycled, the polymerization occurred inside the hollow core and cast it with the PANI film. Subsequently, the Brij 98 template was removed by a thorough washing with water to produce a well-ordered M-PANI film. The structure and the surface morphology of the M-PANI flints were fully characterized by a scanning electron microscope and a transmission electron microscope. The electrochemical, capacitance properties were investigated using electrochemical techniques, e.g., cyclic voltammetry, galvanostatic cycling and electrochemical impedance. The data showed a significant increase in the specific capacitance (as high as 532 F g(-1)) of the M-PANI films when compared with a non M-PANI electrode, which delivered a specific capacitance of 228 F g(-1). (C) The Author(s) 2014. Published by ECS. All rights reserved.