Three-dimensional printing with high-temperature plastic is used to enable spin exchange optical pumping (SEOP) and hyperpolarization of xenon-129 gas. The use of 3D printed structures increases the simplicity of integration of the following key components with a variable temperature SEOP probe: (i) in situ NMR circuit operating at 84 kHz (Larmor frequencies of Xe-129 and H-1 nuclear spins), (ii) <0.3 nm narrowed 200 W laser source, (iii) in situ high-resolution near-IR spectroscopy, (iv) thermoelectric temperature control, (v) retroreflection optics, and (vi) optomechanical alignment system. The rapid prototyping endowed by 3D printing dramatically reduces production time and expenses while allowing reproducibility and integration of "off-the-shelf" components and enables the concept of printing on demand. The utility of this SEOP setup is demonstrated here to obtain near-unity Xe-129 polarization values in a 0.5 L optical pumping cell, including similar to 74 +/- 7% at 1000 Torr xenon partial pressure, a record value at such high Xe density. Values for the Xe-129 polarization exponential build-up rate [(3.63 +/- 0.15) x 10(-2) min(-1)] and in-cell Xe-129 spin-lattice relaxation time (T-1 = 2.19 +/- 0.06 h) for 1000 Torr Xe were in excellent agreement with the ratio of the gas-phase polarizations for Xe-129 and Rb (P-Rb similar to 96%). Hyperpolarization. enhanced Xe-129 gas imaging was demonstrated with a spherical phantom following automated gas transfer from the polarizer. Taken together, these results support the development of a wide range of chemical, biochemical, material science, and biomedical applications.