Three-dimensional (3D) nanoarchitectures have demonstrated substantial advantages in capturing the performance of traditional electrode materials. In this regard, novel Cu@SnS core-shell nanowire array is fabricated via a rational electrochemical assembly strategy. Meanwhile it is also discovered that striking structural and compositional evolution from Cu@SnS core-shell nanowires to hybrid CuS/SnS nanotubes can be achieved by a simple tuning of reaction conditions. As a proof of concept, long-term cycling stability and remarkable rate capability are exhibited by Cu@SnS nanoelectrode in the study of its Li+ storage properties (e.g., it delivers a capacity of similar to 347 mAh g(-1) at 3.33C even after 80 rate-varying cycles), which verifies the effectiveness of the designed 3D configuration in tackling possible electrical/ mechanical failures of the electrode during repeated Li+ uptake/release process. Moreover, because of their potential for achieving high power and energy densities on a small footprint area, the designed metal sulfide nanoelectrodes may be promisingly applied in microenergy storage devices. 0 2014 Elsevier B.V. All rights reserved.