Few-layer molybdenum disulfide/graphene (FL-MoS2/GNS) composites are fabricated by a facile hydrothermal route and a post-annealing with the assistance of various cationic surfactants (dodecyltrimethylammonium bromide, DTAB; octyltrimethylammonium bromide, OTAB; and tetrabutylammonium bromide, TBAB), which have different alkyl-chain lengths and stereo configurations. The effects of these cationic surfactants on the microstructures and electrochemical performances of the FL-MoS2/GNS for lithium storage are investigated. It is demonstrated the cationic surfactants show some ability to control the microstructure (layer number) of FL-MoS2 in composites. The electrochemical performances of FL-MoS2/GNS composites for lithium storage are greatly improved compared to the bare MoS2. Especially, FL-MoS2/GNS with similar to 6 MoS2 layers prepared with the assistance of OTAB exhibits very high reversible capacity of similar to 1200 mAh g(-1) with excellent cycle stability and enhanced rate capability. Electrochemical impedance spectrum also confirms that the FL-MoS2/GNS composite electrodes exhibit much lower electron-transfer resistance than the MoS2. The remarkable electrochemical performances of FL-MoS2/GNS composites can be attributed to the synergistic interaction between FL-MoS2 and graphene and their quasi-3D architectures, which promote lithium diffusion, electron transfer and electrolyte access. (C) 2014 Elsevier B.V. All rights reserved.