화학공학소재연구정보센터
Journal of Power Sources, Vol.251, 305-310, 2014
Ionic conductivity of oxy-apatite La10Si6-xInxO27-delta solid electrolyte ceramics
Oxy-apatite type La10Si6-xInxO27-delta (x = 0.1, 0.2, 0.3, 0.4, 0.5) ceramics are synthesized via the high-temperature solid state reaction method to obtain dense bulk ceramics. Crystal structure and properties of La10Si6-xInxO27-delta ceramics are investigated by X-ray diffraction, scanning electron microscopy, Raman spectroscopy, complex impedance analysis and thermal expansion coefficient measurement. All the compositions of La10Si6-xInxO27-delta ceramics doped with In3+ consist of a hexagonal apatite structure with a space group P63/m. The diffraction peaks of La10Si6-xInxO27-delta ceramics shift to the low angle side with increasing the content of In3+. Lanthanum silicates doped with trivalent In3+ have a higher total conductivity than those without trivalent In3+ at the Si4+ site. La10Si5.8In0.2O26.90 ceramics has the highest total conductivity of 3.14 x 10(-2) S cm(-1) at 1073 K, which is considerably higher than that of undoped La10Si6O27. La10Si5.6In0.4O26.80 has the highest thermal expansion coefficient of 9.01 x 10(-6) K-1 at 1073 K. (C) 2013 Elsevier B.V. All rights reserved.