This work concerns new superhydrophobic surfaces, generated by replacing long fluorocarbon chains, which bioaccumulate, with short chains whilst at the same time retaining oleophobic properties. Here, is described the synthesis of novel 3,4-propylenedioxythiophene derivatives containing both a short fluorocarbon chain (perfluorobutyl) and a hydrocarbon chain of various lengths (ethyl, butyl and hexyl). Superhydrophobic ((water)>150 degrees) surfaces with good oleophobic properties (60 degrees>(hexadecane)>80 degrees) have been obtained by electrodeposition using cyclic voltammetry. Surprisingly, the lowest hystereses and sliding angles (Lotus effect) are obtained with the shortest alkyl chains due to the presence of microstructures made of nanofibers on the surfaces, whereas, the longest alkyl chains leads to nanosheets with high adhesion (Petal effect). Such materials are potential candidates for biomedical applications. (c) 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014, 52, 782-788