Journal of Polymer Science Part B: Polymer Physics, Vol.52, No.10, 708-715, 2014
Effect of Pressure on the Flow Behavior of Polybutene
The rheology of submicron thick polymer melt is examined under high normal pressure conditions by a recently developed photobleached-fluorescence imaging velocimetry technique. In particular, the validity and limitation of Reynold equation solution, which suggests a linear through-thickness velocity profile, is investigated. Polybutene (PB) is sheared between two surfaces in a point contact. The results presented in this work suggest the existence of a critical pressure below which the through-thickness velocity profile is close to linear. At higher pressures however, the profile assumes a sigmoidal shape resembling partial plug flow. The departure of the sigmoidal profile from the linear profile increases with pressure, which is indicative of a second-order phase/glass transition. The nature of the transition is confirmed independently by examining the pressure-dependent dynamics of PB squeeze films. The critical pressure for flow profile transition varies with molecular weight, which is consistent with the pressure-induced glass transition of polymer melt. (c) 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014, 52, 708-715