화학공학소재연구정보센터
Journal of Molecular Catalysis A-Chemical, Vol.359, 1-7, 2012
Ruthenium/magnesium-lanthanum mixed oxide: An efficient reusable catalyst for oxidation of alcohols by using molecular oxygen
An efficient method for the oxidation of benzylic and secondary aromatic alcohols into their corresponding aldehydes or ketones has been achieved by using ruthenium supported magnesium lanthanum mixed oxide as a heterogeneous catalyst in toluene, with molecular oxygen as the sole oxidant. This catalyst can also be operated in solvent free conditions at 393 K and reused for five cycles with consistent yield and selectivity. (C)2012 Elsevier B.V. All rights reserved.