Journal of Chemical Physics, Vol.112, No.6, 2634-2642, 2000
Signatures of non-Markovian relaxation in two-level atoms due to environmental perturbations
The effect of environmental perturbations on a system of two-level atoms is to alter the coupling between the atoms and their surroundings, which manifests itself as a change in the relaxation rates of the atoms. One of the ways in which environmental fluctuations can affect an atom is to modulate its transition frequency in a stochastic manner. We study the response of such two-level atoms to irradiation by a monochromatic laser, and report the results of numerical experiments on the spectrum of scattered light. It is observed that this spectrum is a sensitive indicator of the parameters that describe the stochastic modulation. In addition, the spectra exhibit substantially different features depending on whether the stochastic process follows a diffusion or a jump mechanism. The numerical results are based on a Monte Carlo procedure, which can be applied to stochastic processes in a wide variety of biological, chemical, and physical processes. (C) 2000 American Institute of Physics. [S0021-9606(00)00705-4].
Keywords:DYNAMIC 2-LEVEL SYSTEMS;SPECTRAL DIFFUSION;RESONANCEFLUORESCENCE;SPECTROSCOPY;ABSORPTION;FIELD;COHERENT;EMISSION;LATTICE;SOLIDS