Direct discharging great quantities of organics into water-body not only causes serious environmental pollution but also wastes energy sources. In this paper, a solar responsive dual photoelectrode photocatalytic fuel cell (PFC2) based on TiO2/Ti photoanode and Cu2O/Cu photocathode was designed for hazardous organics treatment with simultaneous electricity generation. Under solar irradiation, the interior bias voltage produced for the Fermi level difference between photoelectrodes drives photoelectrons of TiO2/Ti photoanode to combine with photoholes of Cu2O/Cu photocathode through external circuit thus generating electricity. In the meantime, organics are decomposed by photoholes remained at TiO2/Ti photoanode. By using various hazardous organics including azo dyes as model pollutants, the PFC showed high converting performance of organics into electricity. For example, in 0.05 M phenol solution, a short-circuit current density 0.23 mA cm(-2), open-circuit voltage 0.49 V, maximum power output 0.36 10(-4) W cm(-2) was achieved. On the other hand, removal rate of chroma reached 67%, 87% and 63% in 8 h for methyl orange, methylene blue, Congo red, respectively. (C) 2013 Elsevier B.V. All rights reserved.