화학공학소재연구정보센터
Journal of Hazardous Materials, Vol.217, 194-199, 2012
Photodegradation of indigo carmine and methylene blue dyes in aqueous solution by SiC-TiO2 catalysts prepared by sol-gel
Indigo carmine and methylene blue dyes in aqueous solution were photodegraded using SiC-TiO2 catalysts prepared by sol-gel method. After thermal treatment at 450 degrees C, SiC-TiO2 catalysts prepared in this work showed the presence of SiC and TiO2 anatase phase. Those compounds showed specific surface area values around 22-25 m(2) g(-1), and energy band gap values close to 3.05 eV. In comparison with TiO2 (P25), SiC-TiO2 catalysts showed the highest activity for indigo carmine and methylene blue degradation, but this activity cannot be attributed to the properties above mentioned. Therefore, photocatalytic performance is due to the synergy effect between SiC and TiO2 particles caused by the sol-gel method used to prepare the SiC-TiO2 catalysts. TiO2 nanoparticles are well dispersed onto SiC surface allowing the transfer of electronic charges between SiC and TiO2 semiconductors, which avoid the fast recombination of the electron-hole pair during the photocatalytic process. (C) 2012 Elsevier B.V. All rights reserved.