Journal of Chemical Physics, Vol.110, No.9, 4208-4212, 1999
A local understanding of the quantum chemical geometric phase theorem in terms of diabatic states
A global understanding of the geometric phase theorem associated with conical intersections is gained in terms of local properties of the Hamiltonian along the path actually traversed by means of a resolution of adiabatic states in terms of diabatic states. The analysis also answers certain questions that are left open by formulations in terms of intersection seams. It moreover leads to a method for determining the location of the adiabatic intersections.
Keywords:CONICAL INTERSECTIONS;CROSS-SECTIONS