We present experimental results on the collision of large binary noble gas clusters with a hot graphite surface at an incident velocity of 430 ms(-1). The mixed ArnXm clusters (X=Kr, Xe) with average sizes n+m between 1000 and 13 000 are obtained from pure argon clusters by the pickup technique. The surface scattering dynamics belongs to the thermal evaporation regime and large surviving binary fragments are detected at grazing angles. As expected from simple binding energy considerations, in all cases the surviving clusters are richer in the dopant species X. This enrichment has been measured as a function of incidence angle, incident cluster size, and dopant molar fraction x. For the lowest values of x (about 0.7%), the measured enrichment is the same for Kr and Xe, and decreases slowly with increasing size and incidence angle. On the other hand, when x is raised up to 15%, this enrichment decreases substantially for Xe, and much less for Kr. This unexpected behavior clearly shows that collision induced evaporation cannot be viewed as a mere distillation of an homogeneous binary mixture. The possible role of the incoming cluster structure is discussed in connection with the preparation of the binary clusters by pickup.