Polymerization of Acetylene Derivatives by Tungsten and Molybdenum Chloride-Ethylaluminum Dichloride Catalyst Systems

Gal YS; Lee WC; Choi SK

Korea Polymer Journal, Vol.5, No.1, 10-13, March, 1997

The cocatalytic effect of organo-aluminum compounds (Et₃Al, Et₂AlCl, EtAlCl₂) for the polymerization of acetylene derivatives was studied. In most cases, EtAlCl₂ was found to be a very effective cocatalyst of transition metal chlorides for the metathesis polymerization of acetylene derivatives. It was also found that the molybdeum(V) chloride catalyst was activated by the oxygen atom-containing acetylene monomers. However, the same catalyst systems show no effect for the polymerization of some di-substituted acetylenes, such as 2-butyn-1-ol and 1-(trimethylsilyl)-1-propyne.

[References]

Meziane D, Soun A, Fontanille M, Makromol. Chem., 186, 367 (1985)
Chauser MG, Rodionov YM, Misin VM, Cherkashin MI, Russ. Chem. Rev., 45, 348 (1976)
Gibson HW, Handbook of Conducting Polymers, T.A. Skotheim. Ed., Dekker, New York, vol. 1, pp. 405 (1986)
Choi SK, Chem. Fiber, 71, 13 (1986)
Camus A, Faruffini V, Furlani A, Marsich N, Ortaggi G, Paolesse R, Russo MV, Appl. Org. Chem., 2, 533 (1989)
Ivin KJ, Olefin Metahtesis, Academic Press, London (1983)
Dragutan V, Balaban AT, Dimonie M, Olefin Metathesis and Ring-Opening Polymerization of Cyclo-Olefins, John Wiley & Limited, New York (1985)
Gibson VC, Adv. Mater., 6, 37 (1994)
Masuda T, Hasegawa KI, Higashimura T, Macromolecules, 7, 728 (1974)
Voronkov MG, Pukhnarevich VB, Suschinskara SP, Annenkova VZ, Annenkova VM, Andreeva NJ, J. Polym. Sci. A: Polym. Chem., 18, 53 (1980)
Ohtori T, Masuda T, Higashimura T, Polym. J., 11, 805 (1979)
Masuda T, Kawai M, Higashimura T, Polymer, 23, 744 (1982)
Oh SY, Oguri F, Akagi K, Shirakawa H, J. Polym. Sci. A: Polym. Chem., 31, 781 (1993)
Masuda T, Thieu KQ, Sasaki N, Higashimura T, Macromolecules, 9, 661 (1976)
Higashimura T, Deng YX, Masuda T, Macromolecules, 15, 234 (1982)
Chang TL, Holzknecht LJ, Mark HB, Ridgway TH, Zimmer H, J. Polym. Sci. A: Polym. Chem., 27, 989 (1989)
Yoshimura T, Masuda T, Higashimura T, Macromolecules, 21, 1899 (1988)
Ivin KJ, Lillie S, Rooney JJ, Makromol. Chem., 179, 2787 (1978)
Cho HN, Choi SK, J. Polym. Sci. A: Polym. Chem., 23, 1469 (1985)
Gal YS, Cho HN, Choi SK, Polym.(Korea), 9(5), 361 (1985)
Gal YS, Cho HN, Choi SK, J. Polym. Sci. A: Polym. Chem., 24, 2021 (1986)
Gal YS, Cho HN, Choi SK, Polym.(Korea), 10(7), 688 (1986)
Gal YS, Choi SK, J. Polym. Sci. C: Polym. Lett., 26, 115 (1988)
Ryoo MS, Lee WC, Choi SK, Macromolecules, 23, 3029 (1990)
Jang MS, Kwon SK, Choi SK, Macromolecules, 23, 4135 (1990)
Gal YS, Choi SK, Polym.(Korea), 11(6), 563 (1987)
Gal YS, Jung B, Lee WC, Choi SK, Polym.(Korea), 16(5), 597 (1992)

[Referenced By]

[1] Meziane D, Soun A, Fontanille M, Makromol. Chem., 186, 367 (1985)

[2] Chauser MG, Rodionov YM, Misin VM, Cherkashin MI, Russ. Chem. Rev., 45, 348 (1976)

[3] Gibson HW, Handbook of Conducting Polymers, T.A. Skotheim. Ed., Dekker, New York, vol. 1, pp. 405 (1986)

[4] Choi SK, Chem. Fiber, 71, 13 (1986)

[5] Camus A, Faruffini V, Furlani A, Marsich N, Ortaggi G, Paolesse R, Russo MV, Appl. Org. Chem., 2, 533 (1989)

[6] Ivin KJ, Olefin Metahtesis, Academic Press, London (1983)

[7] Dragutan V, Balaban AT, Dimonie M, Olefin Metathesis and Ring-Opening Polymerization of Cyclo-Olefins, John Wiley & Limited, New York (1985)

[8] Gibson VC, Adv. Mater., 6, 37 (1994)

[9] Masuda T, Hasegawa KI, Higashimura T, Macromolecules, 7, 728 (1974)

[10] Voronkov MG, Pukhnarevich VB, Suschinskara SP, Annenkova VZ, Annenkova VM, Andreeva NJ, J. Polym. Sci. A: Polym. Chem., 18, 53 (1980)

[11] Ohtori T, Masuda T, Higashimura T, Polym. J., 11, 805 (1979)

[12] Masuda T, Kawai M, Higashimura T, Polymer, 23, 744 (1982)

[13] Oh SY, Oguri F, Akagi K, Shirakawa H, J. Polym. Sci. A: Polym. Chem., 31, 781 (1993)

[14] Masuda T, Thieu KQ, Sasaki N, Higashimura T, Macromolecules, 9, 661 (1976)

[15] Higashimura T, Deng YX, Masuda T, Macromolecules, 15, 234 (1982)

[16] Chang TL, Holzknecht LJ, Mark HB, Ridgway TH, Zimmer H, J. Polym. Sci. A: Polym. Chem., 27, 989 (1989)

[17] Yoshimura T, Masuda T, Higashimura T, Macromolecules, 21, 1899 (1988)

[18] Ivin KJ, Lillie S, Rooney JJ, Makromol. Chem., 179, 2787 (1978)

[19] Cho HN, Choi SK, J. Polym. Sci. A: Polym. Chem., 23, 1469 (1985)

[20] Gal YS, Cho HN, Choi SK, Polym.(Korea), 9(5), 361 (1985)

[21] Gal YS, Cho HN, Choi SK, J. Polym. Sci. A: Polym. Chem., 24, 2021 (1986)

[22] Gal YS, Cho HN, Choi SK, Polym.(Korea), 10(7), 688 (1986)

[23] Gal YS, Choi SK, J. Polym. Sci. C: Polym. Lett., 26, 115 (1988)

[24] Ryoo MS, Lee WC, Choi SK, Macromolecules, 23, 3029 (1990)

[25] Jang MS, Kwon SK, Choi SK, Macromolecules, 23, 4135 (1990)

[26] Gal YS, Choi SK, Polym.(Korea), 11(6), 563 (1987)

[27] Gal YS, Jung B, Lee WC, Choi SK, Polym.(Korea), 16(5), 597 (1992)