The single crystals of CrxW1-xSe2 (x=0.25, 0.50, 0.75) have been grown by the chemical vapour transport (CVT) technique using iodine as a transporting agent. The structural characterisation of these crystals has been made by the X-ray diffraction (XRD) method. The lattice parameters, unit cell volume, crystallite size, strain and dislocation densities have also been evaluated for these new crystals. The estimation of growth and deformation fault probabilities is further calculated. The grown crystals were examined under an optical zoom microscope for their surface topography. Thermo gravimetry analysis (TGA) and differential thermogravimetry (DTG) were carried for the CVT grown CrxW1-xSe2 single crystals. The different kinetic parameters: entropy, enthalpy and Gibbs free energy were calculated using Piloyan-Novikova (P-N) and Coats-Redfern (C-R) relations. (C) 2014 Elsevier B.V. All rights reserved.