Journal of Chemical Thermodynamics, Vol.74, 119-125, 2014
Measurement and correlation of solubility of anthraquinone dyestuffs in supercritical carbon dioxide
Solubility data of 1,4-diaminoanthraquinone (C.I. Disperse Violet 1) and 1,4-bis(ethylamino)anthraquinone (C.I. Solvent Blue 59) in supercritical carbon dioxide (sc-CO2) have been measured at the temperatures of (323.15, 353.15, and 383.15) K and over the pressure range from (12.5 to 25.0) MPa by a flow-type apparatus. The solubility of two anthraquinone dyestuffs was obtained over the mole fraction ranges of (1.3 to 26.1) . 10(-7) for 1,4-diaminoanthraquinone (C.I. Disperse Violet 1) and (1.1 to 148.5) . 10(-7) for 1,4-bis(ethylamino) anthraquinone (C.I. Solvent Blue 59). The experimental results have been correlated with the empirical equations of Mendez-Santiago-Teja and Kumar-Johnston expressed in terms of the density of sc-CO2, and also analyzed thermodynamically by the regular solution model with the Flory-Huggins theory and the Peng-Robinson equation of state modified by Stryjek and Vera (PRSV-EOS) with the conventional mixing rules. Good agreement between the experimental and calculated solubilities of the dyestuffs was obtained. (C) 2014 Elsevier Ltd. All rights reserved.