화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.58, 330-339, 2013
Isothermal (vapour plus liquid) equilibria for binary mixtures of diisopropyl ether with (methanol, or ethanol, or 1-butanol): Experimental data, correlations, and predictions
A glass dynamic recirculating still was employed for the measurement of isothermal (vapour + liquid) equilibrium (VLE) data for the binary mixtures of diisopropyl ether (DIPE) + alcohol, viz. (DIPE + methanol), (DIPE + ethanol), and (DIPE + 1-butanol) at T = (305.15, 315.15, and 325.15) K, T = (313.15, 323.15, and 333.15) K and T = (318.15, and 338.15) K, respectively. The combined standard uncertainties in the reported system pressures, temperatures and phase compositions are +/- 0.2 kPa, +/- 0.1 K and +/- 0.003, respectively. Maximum pressure azeotropes were observed for all isotherms of the (DIPE + methanol) and (DIPE + ethanol) systems. The experimental results were correlated using both the gamma-phi and phi-phi approaches. For the correlation of the VLE data with the gamma-phi approach, the Wilson, NRTL and UNIQUAC G(E) models with the truncated two-term virial equation of state (Hayden and O'Connell correlation for second virial coefficient computation) were used. In the phi-phi correlation approach, the Peng-Robinson equation of state was used with the Wong-Sander mixing rules incorporating the same G(E) models used in the gamma-phi approach. Comparisons between the experimental values and predictions using UNIFAC (Dortmund) and the Predictive Soave-Redlich-Kwong (PSRK) model were performed to test the predictive capabilities of these models for the experimental data measured here. The thermodynamic consistency of the experimental data was checked with the Herington area test. (C) 2012 Elsevier Ltd. All rights reserved.