Journal of Chemical Thermodynamics, Vol.54, 10-19, 2012
Experimental excess molar properties of binary mixtures of (3-amino-1-propanol plus isobutanol, 2-propanol) at T=(293.15 to 333.15) K and modelling the excess molar volume by Prigogine-Flory-Patterson theory
Density and viscosity of binary mixtures of (x(1)3-amino-1-propanol + x(2)isobutanol) and (x(1)3-amino-1-propanol + x(2)2-propanol) were measured over the entire composition range and from temperatures (293.15 to 333.15) K at ambient pressure. The excess molar volumes and viscosity deviations were calculated and correlated by the Redlich-Kister (RK) equation. The thermal expansion coefficient and its excess value, isothermal coefficient of excess molar enthalpy, and excess partial molar volumes were determined by using the experimental values of density and are described as a function of composition and temperature. The excess molar volumes are negative over the entire mole fraction range for both mixtures and increase with increasing temperature. The excess molar volumes obtained were correlated by the Prigogine-Flory-Patterson (PFP) model. The viscosity deviations of the binary mixtures are negative over the entire composition range and decrease with increasing temperature. (C) 2012 Elsevier Ltd. All rights reserved.