Journal of Chemical Thermodynamics, Vol.53, 114-118, 2012
Supplementary vapor pressure data of the glycol ethers, 1-methoxy-2-propanol, and 2-methoxyethanol at a pressure range of (15 to 177) kPa
The vapor pressure of pure 1-methoxy-2-propanol and 2-methoxyethanol, commonly used as co-solvents in inks, paints, coatings, organic/water solutions among many other applications, were measured with a dynamic recirculation apparatus at a pressure range of (15 to 177) kPa. The measurements were performed at temperature ranges of (342 to 412) K for 1-methoxy-2-propanol and (346 to 417) K for 2-methoxyethanol. The maximum likelihood method was used to estimate the parameters of the Antoine equation, the parameters of an extended Antoine equation and the Wagner equation were determined by non linear least squares method. The three models showed root mean square deviations (rmsd) of 0.39%, 0.38%, and 0.29%, and 0.37%, 0.33%, and 0.32%, for 1-methoxy-2-propanol and 2-methoxyethanol, respectively. Additionally, the experimental data and correlation were compared with those available in the literature. (C) 2012 Elsevier Ltd. All rights reserved.
Keywords:Dynamic recirculation method;Glycol ethers;1-Methoxy-2-propanol;2-Methoxyethanol;Vapor pressure