Rotationally resolved photoelectron spectra are reported for rovibronically state-selected autoionizing levels of water. These photoelectron spectra are helpful for the spectroscopic assignment of the autoionizing-levels and provide considerable dynamical information on the mechanisms for the transfer of energy and angular momentum between the ion core and the Rydberg electron. As a result of angular momentum restrictions, photoelectron spectra for J = 0 autoionizing levels provide a direct partial wave analysis for the ejected photoelectrons.