The effect of a liquid dispersed on the wall flow structure in static mixer is analyzed by using an electrochemical method. Both laminar and turbulent flows have been investigated. The axial wall velocity gradient and turbulent intensity have been studied along the static mixer in both flow regimes and for different dispersed phase concentrations. The spectral analysis of the wall velocity gradient fluctuations was analyzed in the turbulent regime. For volume fraction higher than 5%, the effect of the dispersed liquid phase is very important for all the studied parameters. The turbulence associated to the dispersed phase leads to an increase of the energy dissipation in the static mixer and also to a modification of energy dissipation mechanism. (c) 2006 Elsevier Ltd. All rights reserved.