The hydrogen storage ability of TiCx with stacking faults (SFs) is studied in this work. It is found that the absorption of hydrogen atoms is possible in both TiCx with and without SFs. And, besides the carbon vacancy sites, the hydrogen atoms can also occupy the tetrahedral sites in the SFs layers. More importantly, it is confirmed that the diffusion of hydrogen in TiCx with SFs is much easier than that in TiCx without SFs, especially the diffusion around the SFs layers. The energy bather for diffusion of the hydrogen atom in the SFs layers and diffusion from the SF layer to the next layer is only 0.099 eV and 0.185 eV, respectively. Therefore, bringing in the SFs in TiCx with ordered carbon vacancies will be an effective method to solve the diffusion problem during the processes of hydrogen storage. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.