화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.38, No.31, 13664-13672, 2013
Enhanced dormancy due to para-to-ortho hydrogen conversion in insulated cryogenic pressure vessels for automotive applications
A dynamic model has been developed to characterize dormancy and hydrogen loss from an insulated cryogenic pressure vessel that is filled with 99.79%-para liquid hydrogen to reach supercritical conditions. The model considers the thermodynamics and kinetics of the endothermic para-to-ortho conversion that occurs when the stored H-2 heats after the vessel is exposed to ambient conditions for an extended time. The thermal, thermodynamic, and kinetic aspects of the model were validated against experimental data obtained on a 151-L tank designed for service at nominal pressures up to 350 bar. Depending on the initial pressure, temperature, amount of H-2, and the rate of heat gain from the ambient, the endothermic para-to-ortho conversion can extend the loss-free dormancy time by up to 85%. Under conditions in which the endothermic conversion does not materially affect dormancy, it can still significantly reduce the H-2 loss rate and it can even introduce a secondary dormancy period. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.